(S)-α-tert-Butyl-1-naphthylmethylamine

Base Information

Chemical Name:(S)-α-tert-Butyl-1-naphthylmethylamine
CAS No.:324034-56-2
Molecular Formula:
Molecular Weight:213.32
Hs Code.:
Mol file:324034-56-2.mol

Synonyms:(S)-2,2-Dimethyl-1-(1-naphthyl)propylamine;(S)-α-tert-Butyl-1-naphthalenemethanamine;(S)-α-tert-Butyl-1-naphthylmethylamine;(αS)-α-(1,1-Dimethylethyl)-1-naphthalenemethanamine;(ALPHAS)-ALPHA-(1,1-DIMETHYLETHYL)-1-NAPHTHALENEMETHANAMINE

Suppliers and Price of (S)-α-tert-Butyl-1-naphthylmethylamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
(S)-2,2-Dimethyl-1-(1-naphthyl)propylamine ≥98% (HPLC)
100mg
$ 176.00

Sigma-Aldrich
(S)-2,2-Dimethyl-1-(1-naphthyl)propylamine ≥98% (HPLC)
500mg
$ 684.00

AK Scientific
(S)-2,2-Dimethyl-1-(1-naphthyl)propylamine
100mg
$ 270.00

Total 2 raw suppliers

Chemical Property of (S)-α-tert-Butyl-1-naphthylmethylamine

Chemical Property:

Storage Temp.:2-8°C

Purity/Quality:

97% ^*data from raw suppliers

(S)-2,2-Dimethyl-1-(1-naphthyl)propylamine ≥98% (HPLC) ^*data from reagent suppliers

Safty Information:

Pictogram(s): 8684336
Hazard Codes:Xi
Statements: 37/38-41
Safety Statements: 26-39

MSDS Files:

Useful:

Technology Process of (S)-α-tert-Butyl-1-naphthylmethylamine

There total 11 articles about (S)-α-tert-Butyl-1-naphthylmethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 677-22-5
tert-butylmagnesium chloride

: 86-53-3
1-Cyanonaphthalene

: 324034-56-2
α-(1,1-Dimethylethyl)-1-naphthalinmethanamin

Guidance literature:: tert-butylmagnesium chloride; 1-Cyanonaphthalene; With copper(I) bromide; In diethyl ether; for 24h; Inert atmosphere; Reflux;

With sodium tetrahydroborate; In methanol; diethyl ether; at -78 - 25 ℃; for 16h; Inert atmosphere;
DOI:10.1002/chem.201301572

Reference yield:

: 630-18-2
tert-butyl isocyanide

: 324034-55-1,324034-56-2
(R)-2,2-dimethyl-1-(naphthalen-1-yl)propan-1-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: BuLi / diethyl ether / 2 h / 0 °C

1.2: 85 percent / diethyl ether / 1.5 h / 20 °C

2.1: LiAlH₄ / diethyl ether / 22 h / Heating

With lithium aluminium tetrahydride; n-butyllithium; In diethyl ether; 1.1: Metallation / 1.2: Addition / 2.1: Reduction;
DOI:10.1016/S0957-4166(00)00334-7

Reference yield:

: 630-18-2
tert-butyl isocyanide

: 324034-56-2
(S)-2,2-dimethyl-1-(naphthalen-1-yl)propan-1-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: BuLi / diethyl ether / 2 h / 0 °C

1.2: 85 percent / diethyl ether / 1.5 h / 20 °C

2.1: LiAlH₄ / diethyl ether / 22 h / Heating

With lithium aluminium tetrahydride; n-butyllithium; In diethyl ether; 1.1: Metallation / 1.2: Addition / 2.1: Reduction;
DOI:10.1016/S0957-4166(00)00334-7