4-(3-Chlorophenyl)but-1-ene

Base Information

• Chemical Name: 4-(3-Chlorophenyl)but-1-ene
• CAS No.: 91426-46-9
• Molecular Formula: C10H11Cl
• Molecular Weight: 166.65
• Hs Code.: 2903999090
• Mol file: 91426-46-9.mol

Synonyms:3-(But-3-en-1-yl)chlorobenzene;4-(3-Chlorophenyl)but-1-ene;4-(3-Chlorophenyl)but-1-ene, 1-(But-3-en-1-yl)-3-chlorobenzene, 3-Homoallylchlorobenzene;1-(But-3-en-1-yl)-3-chlorobenzene

Chemical Property of 4-(3-Chlorophenyl)but-1-ene

Chemical Property:

• Vapor Pressure: 0.254mmHg at 25°C
• Boiling Point: 212.3°C at 760 mmHg
• Flash Point: 84.3°C
• PSA: 0.00000
• Density: 1.026g/cm³
• LogP: 3.45860

Purity/Quality:

95% ^*data from raw suppliers

4-(3-Chlorophenyl)-1-butene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-(3-Chlorophenyl)but-1-ene

There total 7 articles about 4-(3-Chlorophenyl)but-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

m-Chlorobenzaldehyde (587-04-2) + allylsamarium bromide (346713-20-0) → 1-(but-3-en-1-yl)-3-chlorobenzene (91426-46-9)

Guidance literature:

m-Chlorobenzaldehyde; allylsamarium bromide; In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere;

With phosphonic acid diethyl ester; In tetrahydrofuran; Inert atmosphere;

DOI:10.1039/c3cc45611k

Reference yield:

Allyl acetate (591-87-7) + 3-chlorobenzaldehyde hydrazone (306773-38-6) → 1-(but-3-en-1-yl)-3-chlorobenzene (91426-46-9)

Guidance literature:

Allyl acetate; With bis(η3-allyl-μ-chloropalladium(II)); Tri(p-tolyl)phosphine; In tetrahydrofuran; for 0.5h; Schlenk technique; Sealed tube; Inert atmosphere;

3-chlorobenzaldehyde hydrazone; With lithium tert-butoxide; In tetrahydrofuran; at 45 ℃; for 24h; chemoselective reaction; Schlenk technique; Sealed tube; Inert atmosphere;

DOI:10.1002/anie.201809112

Reference yield:

3-(3-chlorophenyl)propanal (136415-83-3) + Methyltriphenylphosphonium bromide (1779-49-3) → 1-(but-3-en-1-yl)-3-chlorobenzene (91426-46-9)

Guidance literature:

Methyltriphenylphosphonium bromide; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.5h; Inert atmosphere;

3-(3-chlorophenyl)propanal; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1002/adsc.202001612

upstream raw materials:

3-chlorobenzyl magnesium bromide

allyl bromide

m-Chlorobenzaldehyde

allylsamarium bromide

Downstream raw materials:

1-<3-Chlorphenyl>-1-trichlorsilyl-butan

Trichlor-4-<3-chlorphenyl>-butylsilan