Fluorotris(triphenylphosphine)copper(I)

Base Information

• Chemical Name: Fluorotris(triphenylphosphine)copper(I)
• CAS No.: 25753-74-6
• Molecular Formula: C54H45CuFP3
• Molecular Weight: 869.417
• Mol file: 25753-74-6.mol

Synonyms:Fluorotris(triphenylphosphine)copper(I) ;Fluorotris(triphenylphosphine)copper(I) 95% (by HMR)

Chemical Property of Fluorotris(triphenylphosphine)copper(I)

Chemical Property:

• Melting Point: 144-157°C
• PSA: 40.77000
• LogP: 7.33590

Purity/Quality:

98%,99%, ^*data from raw suppliers

FLUOROTRIS(TRIPHENYLPHOSPHINE)COPPER(I) 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Complex used in asymmetric aldol reaction

Technology Process of Fluorotris(triphenylphosphine)copper(I)

There total 3 articles about Fluorotris(triphenylphosphine)copper(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

methanol (67-56-1) + copper (II)-fluoride + triphenylphosphine (603-35-0) → (PPh3)3CuF (25753-74-6)

Guidance literature:

for 2.5h; Reflux; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201209020

Reference yield:

copper (II)-fluoride + triphenylphosphine (603-35-0) → (PPh3)3CuF (25753-74-6) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8)

Guidance literature:

With H₂O; In methanol; byproducts: OPPh3; reflux;

DOI:10.1016/j.jorganchem.2009.08.017

Reference yield:

CuF2*(x)H2O → (PPh3)3CuF (25753-74-6)

Guidance literature:

With triphenylphosphine; In methanol; stirring in hot methanol; filtration, pptn. on cooling, elem. anal.;

upstream raw materials:

triphenylphosphine

methanol

Refernces

• 1、 Gathy, Thomas,Peeters, Daniel,Leyssens, Tom. "Mechanism of ketone hydrosilylation by Cu(I) catalysts: A theoretical study". . p. 3943 - 3950. Retrieved 2010/03/01.