3-Bromoacetophenone diethyl ke

Base Information

Chemical Name:3-Bromoacetophenone diethyl ke
CAS No.:480439-43-8
Molecular Formula:C12H17BrO2
Molecular Weight:273.168
Hs Code.:
Mol file:480439-43-8.mol

Synonyms:3-Bromoacetophenone diethyl ke;3-Bromoacetophenone diethyl ketal, 98%;3'-BroMoacetophenone diethyl ketal, 96%, stab. with PotassiuM carbonate

Suppliers and Price of 3-Bromoacetophenone diethyl ke

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Alfa Aesar
3'-Bromoacetophenone diethyl ketal, 96%, stab. with Potassium carbonate
25g
$ 193.00

Alfa Aesar
3'-Bromoacetophenone diethyl ketal, 96%, stab. with Potassium carbonate
5g
$ 58.70

Total 3 raw suppliers

Chemical Property of 3-Bromoacetophenone diethyl ke

Chemical Property:

PSA：18.46000
LogP:3.69480

Purity/Quality:

99% ^*data from raw suppliers

3'-Bromoacetophenone diethyl ketal, 96%, stab. with Potassium carbonate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 3-Bromoacetophenone diethyl ke

There total 1 articles about 3-Bromoacetophenone diethyl ke which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 2142-63-4
1-(3-Bromophenyl)ethanone

: 122-51-0
orthoformic acid triethyl ester

: 480439-43-8
2-bromo-4-(1,1-diethoxyethyl)benzene

Guidance literature:: With hydrogenchloride; In ethanol; water; for 4h; Inert atmosphere; Schlenk technique; Reflux;
DOI:10.1039/c3dt52565a

Reference yield: 85.0%

: 480439-43-8
2-bromo-4-(1,1-diethoxyethyl)benzene

: 436-59-9
dimesitylfluoroborane

: 1567979-53-6
Mes₂B(C₆H₄)C(CH₃)O

Guidance literature:: 2-bromo-4-(1,1-diethoxyethyl)benzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h; Inert atmosphere; Schlenk technique;

dimesitylfluoroborane; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 12h; Inert atmosphere; Schlenk technique;

With hydrogenchloride; In tetrahydrofuran; hexane; water; at 20 ℃; for 4h; Inert atmosphere; Schlenk technique;
DOI:10.1039/c3dt52565a

Reference yield:

: 480439-43-8
2-bromo-4-(1,1-diethoxyethyl)benzene

: 1567979-63-8
Mes₂B(C₆H₄)C(CH₃)(C₄H₄N)2

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 1.5 h / -78 °C / Inert atmosphere; Schlenk technique

1.2: 12 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

1.3: 4 h / 20 °C / Inert atmosphere; Schlenk technique

2.1: boron trifluoride diethyl etherate / 6.5 h / 20 °C / Inert atmosphere; Schlenk technique

With n-butyllithium; boron trifluoride diethyl etherate; In tetrahydrofuran; hexane;
DOI:10.1039/c3dt52565a