Methyl 4-methylbenzo[b]thiophene-2-carboxylate

Base Information

Chemical Name:Methyl 4-methylbenzo[b]thiophene-2-carboxylate
CAS No.:146137-98-6
Molecular Formula:C₁₁H₁₀O₂S
Molecular Weight:206.265
Hs Code.:
DSSTox Substance ID:DTXSID00597324
Wikidata:Q82492849

Synonyms:Methyl 4-methylbenzo[b]thiophene-2-carboxylate;146137-98-6;Methyl 4-methyl-1-benzothiophene-2-carboxylate;Benzo[b]thiophene-2-carboxylic acid, 4-methyl-, methyl ester;Methyl4-methylbenzo[b]thiophene-2-carboxylate;SCHEMBL806489;DTXSID00597324;MXRCGMSSEDWQKY-UHFFFAOYSA-N;A884550

Suppliers and Price of Methyl 4-methylbenzo[b]thiophene-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 10 raw suppliers

Chemical Property of Methyl 4-methylbenzo[b]thiophene-2-carboxylate

Chemical Property:

Vapor Pressure:0.000281mmHg at 25°C
Boiling Point:322.3°C at 760 mmHg
Flash Point:148.7°C
Density:1.233g/cm³
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:206.04015073
Heavy Atom Count:14
Complexity:229

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C2C=C(SC2=CC=C1)C(=O)OC

Technology Process of Methyl 4-methylbenzo[b]thiophene-2-carboxylate

There total 8 articles about Methyl 4-methylbenzo[b]thiophene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 823-96-1
Trimethylboroxine

: 360575-29-7
methyl 4-bromobenzo[b]thiophene-2-carboxylate

: 146137-98-6
methyl 4-methylbenzo[b]thiophene-2-carboxylate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In N,N-dimethyl-formamide; Heating;
DOI:10.1016/j.bmcl.2005.04.046

Reference yield: 74.0%

: methyl 3-chloro-4-methyl-1-benzothiophene-2-carboxylate

: 146137-98-6
methyl 4-methylbenzo[b]thiophene-2-carboxylate

: dimethyl 4,4'-dimethyl-3,3'-bi(1-benzo[b]thiophene)-2,2'-dicarboxylate

Guidance literature:: With copper; In N,N-dimethyl-formamide; at 170 ℃; for 16h;
DOI:10.1135/cccc20031020

Reference yield:

: 13061-96-6
dihydroxy-methyl-borane

: 360575-29-7
methyl 4-bromobenzo[b]thiophene-2-carboxylate

: 146137-98-6
methyl 4-methylbenzo[b]thiophene-2-carboxylate

Guidance literature:: With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In 1,4-dioxane; water; at 100 ℃; for 3h; Inert atmosphere;