Bis(2,4,6-trimethylphenyl)phosphorus chloride

Base Information

Chemical Name:Bis(2,4,6-trimethylphenyl)phosphorus chloride
CAS No.:67950-05-4
Molecular Formula:C18H23P
Molecular Weight:304.799
Hs Code.:
European Community (EC) Number:623-485-6
DSSTox Substance ID:DTXSID60545265
Nikkaji Number:J1.152.017K
Wikidata:Q82422704
Mol file:67950-05-4.mol

Synonyms:Bis(2,4,6-trimethylphenyl)phosphorus chloride;67950-05-4;Chlorodimesitylphosphane;Chlorodimesitylphosphine;chloro-bis(2,4,6-trimethylphenyl)phosphane;SCHEMBL5362839;DTXSID60545265;CS-0084980;Bis(2,4,6-trimethylphenyl)phosphinous chloride;Bis(2,4,6-trimethylphenyl)phosphorus chloride, 95%

Suppliers and Price of Bis(2,4,6-trimethylphenyl)phosphorus chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Bis(2,4,6-trimethylphenyl)phosphine 97%
500 mg
$ 83.60

Sigma-Aldrich
Bis(2,4,6-trimethylphenyl)phosphorus chloride 95%
1g
$ 78.10

American Custom Chemicals Corporation
BIS(2,4,6-TRIMETHYLPHENYL)PHOSPHORUS CHLORIDE 95.00%
1G
$ 671.50

Total 6 raw suppliers

Chemical Property of Bis(2,4,6-trimethylphenyl)phosphorus chloride

Chemical Property:

Melting Point:80-85°C
PSA：13.59000
LogP:4.16630
XLogP3:6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:304.1147654
Heavy Atom Count:20
Complexity:265

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bis(2,4,6-trimethylphenyl)phosphine 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:C
Statements: 34
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C(=C1)C)P(C2=C(C=C(C=C2C)C)C)Cl)C

Technology Process of Bis(2,4,6-trimethylphenyl)phosphorus chloride

There total 7 articles about Bis(2,4,6-trimethylphenyl)phosphorus chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 576-83-0
2,4,6-trimethylphenyl bromide

: 67950-05-4
bis(2,4,6-trimethylphenyl)chlorophosphine

Guidance literature:: 2,4,6-trimethylphenyl bromide; With magnesium; In diethyl ether; at 20 ℃; for 7h; Reflux;

With phosphorus trichloride; In diethyl ether; at 0 - 20 ℃;
DOI:10.1021/jacs.1c07838

Reference yield: 31.0%

: 5806-59-7
mesityllithium

: 6781-96-0
dichloro(mesityl)phosphane

: 67950-05-4
bis(2,4,6-trimethylphenyl)chlorophosphine

Guidance literature:: With phosphorus trichloride; In diethyl ether; at 0 - 25 ℃; for 15h;
DOI:10.1016/S0022-328X(00)99656-6

Reference yield:

: 2633-66-1
2-mesitylmagnesium bromide

: 23897-15-6
tris(2,4,6-trimethylphenyl)phosphine

: 67950-05-4
bis(2,4,6-trimethylphenyl)chlorophosphine

: 86280-09-3
Brombis(2,4,6-trimethylphenyl)phosphan

Guidance literature:: With phosphorus trichloride; In tetrahydrofuran; at -50 ℃; Yield given. Title compound not separated from byproducts; further reagent: PBr₃;