2,2-Dimethyl-4-(oxiran-2-yl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxole

Base Information

Chemical Name:2,2-Dimethyl-4-(oxiran-2-yl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxole
CAS No.:226709-43-9
Molecular Formula:C9H14O4
Molecular Weight:186.21
Hs Code.:2932990090
DSSTox Substance ID:DTXSID40376958,DTXSID701211855
Mol file:226709-43-9.mol

Synonyms:226709-43-9;2,2-Dimethyl-4-(2-oxiranyl)tetrahydrofuro-[3,4-d][1,3]dioxole;2,2-dimethyl-4-(oxiran-2-yl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxole;2,2-dimethyl-4-(2-oxiranyl)tetrahydrofuro[3,4-d][1,3]dioxole;2-{2,2-dimethyl-tetrahydro-2H-furo[3,4-d][1,3]dioxol-4-yl}oxirane;449778-59-0;DTXSID40376958;DTXSID701211855;MFCD03425721;AKOS005069687;12R-0004;J-506814;1,4:5,6-Dianhydro-2,3-O-(1-methylethylidene)hexitol;Hexitol, 1,2:3,6-dianhydro-4,5-O-(1-methylethylidene)-;2,2-Dimethyl-4-(oxiran-2-yl)tetrahydrofuro[3,4-d][1,3]dioxole

Suppliers and Price of 2,2-Dimethyl-4-(oxiran-2-yl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

SynQuest Laboratories
2-{2,2-Dimethyl-tetrahydro-2H-furo[3,4-d][1,3]dioxol-4-yl}oxirane 95%
1 g
$ 488.00

Matrix Scientific
2,2-Dimethyl-4-(2-oxiranyl)tetrahydrofuro-[3,4-d][1,3]dioxole >95%
1g
$ 454.00

Matrix Scientific
2,2-Dimethyl-4-(2-oxiranyl)tetrahydrofuro-[3,4-d][1,3]dioxole >95%
500mg
$ 362.00

American Custom Chemicals Corporation
2,2-DIMETHYL-4-(2-OXIRANYL)TETRAHYDROFURO[3,4-D][1,3]DIOXOLE 95.00%
1G
$ 866.13

American Custom Chemicals Corporation
2,2-DIMETHYL-4-(2-OXIRANYL)TETRAHYDROFURO[3,4-D][1,3]DIOXOLE 95.00%
500MG
$ 791.52

AK Scientific
2,2-Dimethyl-4-(2-oxiranyl)tetrahydrofuro-[3,4-d][1,3]dioxole
500mg
$ 538.00

Total 3 raw suppliers

Chemical Property of 2,2-Dimethyl-4-(oxiran-2-yl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxole

Chemical Property:

Melting Point:81-82°
PSA：40.22000
LogP:0.30410
XLogP3:-0.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:186.08920892
Heavy Atom Count:13
Complexity:228

Purity/Quality:

98%min ^*data from raw suppliers

2-{2,2-Dimethyl-tetrahydro-2H-furo[3,4-d][1,3]dioxol-4-yl}oxirane 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(OC2COC(C2O1)C3CO3)C

Technology Process of 2,2-Dimethyl-4-(oxiran-2-yl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxole

There total 2 articles about 2,2-Dimethyl-4-(oxiran-2-yl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 188778-70-3
O⁴,O⁵-isopropylidene-3,6-anhydro-1-deoxy-1-iodo-D-glucitol

: 226709-43-9
O⁴,O⁵-isopropylidene-1,2:3,6-dianhydro-D-glucitol

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 0 - 20 ℃; for 6h;
DOI:10.1016/j.tet.2010.09.060

Reference yield:

: 652-67-5
Isosorbide

: 226709-43-9
O⁴,O⁵-isopropylidene-1,2:3,6-dianhydro-D-glucitol

Guidance literature:: Multi-step reaction with 2 steps

1: chloro-trimethyl-silane; sodium iodide / acetonitrile

2: sodium hydride / 1,4-dioxane; mineral oil / 50 °C / Cooling with ice

With chloro-trimethyl-silane; sodium hydride; sodium iodide; In 1,4-dioxane; acetonitrile; mineral oil;
DOI:10.1016/j.carres.2011.05.034