1-Phenylvinyl phosphate

Base Information

• Chemical Name: 1-Phenylvinyl phosphate
• CAS No.: 76625-78-0
• Molecular Formula: C₈H₇O₄P*2Na
• Molecular Weight: 244.094
• Hs Code.: 2919900090
• DSSTox Substance ID: DTXSID10997957
• Wikidata: Q82990302
• Mol file: 76625-78-0.mol

Synonyms:1-phenylvinyl phosphate;1-phenylvinyl phosphate, disodium salt

Chemical Property of 1-Phenylvinyl phosphate

Chemical Property:

• Vapor Pressure: 6.4E-07mmHg at 25°C
• Boiling Point: 394.2°C at 760 mmHg
• Flash Point: 192.2°C
• PSA: 77.51000
• LogP: 2.76180
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 200.02384576
• Heavy Atom Count: 13
• Complexity: 226

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C(C1=CC=CC=C1)OP(=O)(O)O

Technology Process of 1-Phenylvinyl phosphate

There total 2 articles about 1-Phenylvinyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

monoanilinium 1-phenylethenyl hydrogen phosphate (70334-78-0) → disodium 1-phenylvinyl phosphate (76625-78-0)

Guidance literature:

With sodium hydroxide;

DOI:10.1021/ja00395a030

Reference yield:

(2-bromo-1,3-diphenyl-3-oxo-1-propyl)phosphonic acid (84959-95-5) + acetophenone (98-86-2) → disodium 1-phenylvinyl phosphate (76625-78-0)

Guidance literature:

With 2,2,6,6-tetramethyl-piperidine; Product distribution; Ambient temperature; other bases, other ketones, other solvents;

DOI:10.1021/ja00347a051

upstream raw materials:

monoanilinium 1-phenylethenyl hydrogen phosphate

(2-bromo-1,3-diphenyl-3-oxo-1-propyl)phosphonic acid

acetophenone

Refernces

• 1、 Satterthwait, Arnold C.,Westheimer, F. H.. "Monomeric Metaphosphate Anion: Reaction with Carbonyl Groups". . p. 1177 - 1180. Retrieved 2007/10/02.