2-Bromo-6-propoxynaphthalene

Base Information

• Chemical Name: 2-Bromo-6-propoxynaphthalene
• CAS No.: 97476-14-7
• Molecular Formula: C13H13BrO
• Molecular Weight: 265.14572
• Hs Code.: 2909309090
• DSSTox Substance ID: DTXSID40468322
• Wikidata: Q82295486
• Mol file: 97476-14-7.mol

Synonyms:2-Bromo-6-propoxynaphthalene;97476-14-7;2-Bromo-6-n-propyloxynaphthalene;C13H13BrO;SCHEMBL4057003;DTXSID40468322;XUMPVNAHICLIGO-UHFFFAOYSA-N;XDA47614;2-(n-propyloxy)-6-bromonaphthalene;AKOS008948289;BS-24739;CS-0195075;E91433;A858624

Chemical Property of 2-Bromo-6-propoxynaphthalene

Chemical Property:

• PSA: 9.23000
• LogP: 4.39110
• Storage Temp.: 2-8°C
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 264.01498
• Heavy Atom Count: 15
• Complexity: 195

Purity/Quality:

99% ^*data from raw suppliers

2-Bromo-6-propoxynaphthalene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCOC1=CC2=C(C=C1)C=C(C=C2)Br

Technology Process of 2-Bromo-6-propoxynaphthalene

There total 7 articles about 2-Bromo-6-propoxynaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

6-bromo-naphthalen-2-ol (15231-91-1) + propyl bromide (106-94-5) → 2-propyloxy-6-bromonaphthalene (97476-14-7)

Guidance literature:

With potassium carbonate; In acetonitrile; for 3h; Reflux;

DOI:10.1039/c2jm32448b

Reference yield: 95.4%

6-bromo-naphthalen-2-ol (15231-91-1) + 1-iodo-propane (107-08-4) → 2-propyloxy-6-bromonaphthalene (97476-14-7)

Guidance literature:

With potassium carbonate; In acetone; at 59 ℃; for 48h; Large scale;

DOI:10.1021/op800144h

Reference yield: 80.0%

6-bromo-naphthalen-2-ol (15231-91-1) → 2-propyloxy-6-bromonaphthalene (97476-14-7)

Guidance literature:

With potassium carbonate; In acetonitrile; for 24h; Reflux;

DOI:10.1016/j.bmc.2009.01.074

upstream raw materials:

propan-1-ol

6-bromo-naphthalen-2-ol

1-iodo-propane

propyl bromide

Downstream raw materials:

6-propoxy-2-naphthaldehyde

1-benzyl-4-(1-naphthyl)-4-hydroxypiperidine

Refernces

• 1、 Arakawa, Yuki,Nakajima, Shunpei,Kang, Sungmin,Shigeta, Masayuki,Konishi, Gen-Ichi,Watanabe, Junji. "Design of an extremely high birefringence nematic liquid crystal based on a dinaphthyl-diacetylene mesogen". supporting information; experimental part. p. 13908 - 13910. Retrieved 2012/08/08.
• 2、 Benanti, Travis L.,Saejueng, Pranorm,Venkataraman. "Segregated assemblies in bridged electron-rich and electron-poor π-conjugated moieties". . p. 692 - 694. Retrieved 2007/10/03.