(S)-(-)-1-Benzoyloxy-2-benzyloxy-3-tosyloxypropane

Base Information

Chemical Name:(S)-(-)-1-Benzoyloxy-2-benzyloxy-3-tosyloxypropane
CAS No.:109371-33-7
Molecular Formula:C₂₄H₂₄O₆S
Molecular Weight:440.517
Hs Code.:2916 31 00
DSSTox Substance ID:DTXSID00538111
Wikidata:Q82413336
Mol file:109371-33-7.mol

Synonyms:109371-33-7;(S)-(-)-1-BENZOYLOXY-2-BENZYLOXY-3-TOSYLOXYPROPANE;[(2S)-3-(4-methylphenyl)sulfonyloxy-2-phenylmethoxypropyl] benzoate;(S)-2-(Benzyloxy)-3-(tosyloxy)propyl benzoate;(2S)-2-(BENZYLOXY)-3-[(4-METHYLBENZENESULFONYL)OXY]PROPYL BENZOATE;DTXSID00538111;PXMMPVOAHGXZSG-QFIPXVFZSA-N;(2S)-2-(Benzyloxy)-3-[(4-methylbenzene-1-sulfonyl)oxy]propyl benzoate

Suppliers and Price of (S)-(-)-1-Benzoyloxy-2-benzyloxy-3-tosyloxypropane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
(S)-(-)-1-Benzoyloxy-2-benzyloxy-3-tosyloxypropane for synthesis. CAS 109371-33-7, molar mass 440.51 g/mol., for synthesis
8141430001
$ 78.50

American Custom Chemicals Corporation
(S)-(-)-1-BENZOYLOXY-2-BENZYLOXY-3-TOSYLOXY PROPANE 95.00%
5MG
$ 497.74

Total 3 raw suppliers

Chemical Property of (S)-(-)-1-Benzoyloxy-2-benzyloxy-3-tosyloxypropane

Chemical Property:

Melting Point:97-99°C
Boiling Point:585.9±50.0 °C(Predicted)
PSA：87.28000
Density:1.247±0.06 g/cm3(Predicted)
LogP:5.22350
Storage Temp.:Store below +30°C.
XLogP3:4.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:11
Exact Mass:440.12935965
Heavy Atom Count:31
Complexity:623

Purity/Quality:

99.0%min ^*data from raw suppliers

(S)-(-)-1-Benzoyloxy-2-benzyloxy-3-tosyloxypropane for synthesis. CAS 109371-33-7, molar mass 440.51 g/mol., for synthesis ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: S22:Do not inhale dust.; S24/25:Avoid contact with skin and eyes.;

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OCC(COC(=O)C2=CC=CC=C2)OCC3=CC=CC=C3
Isomeric SMILES:CC1=CC=C(C=C1)S(=O)(=O)OC[C@H](COC(=O)C2=CC=CC=C2)OCC3=CC=CC=C3

Technology Process of (S)-(-)-1-Benzoyloxy-2-benzyloxy-3-tosyloxypropane

There total 5 articles about (S)-(-)-1-Benzoyloxy-2-benzyloxy-3-tosyloxypropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 109371-30-4
(S)-2-benzyloxy-3-(toluene-4-sulfonyloxy)-propan-1-ol

: 98-88-4
benzoyl chloride

: 109371-33-7
Benzoic acid (S)-2-benzyloxy-3-(toluene-4-sulfonyloxy)-propyl ester

Guidance literature:: In pyridine;
DOI:10.1016/S0040-4039(00)95774-5

Reference yield:

: 105409-38-9
1,3-di-O-acetyl-2-O-benzylglycerol

: 109371-33-7
Benzoic acid (S)-2-benzyloxy-3-(toluene-4-sulfonyloxy)-propyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: diisopropyl ether; H₂O / 2 h / Ambient temperature; Lipase aus Schweinepankreas, pH 7

2: 82 percent / pyridine

3: 80 percent / KOH, / methanol; H₂O

4: 88 percent / pyridine

With potassium hydroxide; In pyridine; methanol; di-isopropyl ether; water;
DOI:10.1016/S0040-4039(00)95774-5

Reference yield:

: 109429-00-7
<(R)-2-(benzyloxy)-3-hydroxypropyl> acetate

: 109371-33-7
Benzoic acid (S)-2-benzyloxy-3-(toluene-4-sulfonyloxy)-propyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / pyridine

2: 80 percent / KOH, / methanol; H₂O

3: 88 percent / pyridine

With potassium hydroxide; In pyridine; methanol; water;
DOI:10.1016/S0040-4039(00)95774-5