ethyl 4-[tert-butyl(dimethyl)silyl]oxynaphthalene-2-carboxylate

Base Information

Chemical Name:ethyl 4-[tert-butyl(dimethyl)silyl]oxynaphthalene-2-carboxylate
CAS No.:894779-44-3
Molecular Formula:C₁₉H₂₆O₃Si
Molecular Weight:330.499
Hs Code.:

Synonyms:2-Naphthalenecarboxylic acid, 4-[[(1,1-diMethylethyl)diMethylsilyl]oxy]-, ethyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ethyl 4-[tert-butyl(dimethyl)silyl]oxynaphthalene-2-carboxylate

Chemical Property:

Vapor Pressure:1.61E-06mmHg at 25°C
Boiling Point:397.3°C at 760 mmHg
Flash Point:161.2°C
PSA：35.53000
Density:1.031g/cm³
LogP:5.40050

Purity/Quality:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of ethyl 4-[tert-butyl(dimethyl)silyl]oxynaphthalene-2-carboxylate

There total 1 articles about ethyl 4-[tert-butyl(dimethyl)silyl]oxynaphthalene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 91307-39-0
ethyl 1,2,3,4-tetrahydro-4-hydroxy-2-naphthoate

: 18162-48-6
tert-butyldimethylsilyl chloride

: 894779-44-3
4-(tert-butyldimethylsilanyloxy)naphthalene-2-carboxylic acid ethyl ester

Guidance literature:: With 1H-imidazole; In dichloromethane; at 20 ℃; for 18h;
DOI:10.1021/jm0510732

Reference yield:

: 894779-44-3
4-(tert-butyldimethylsilanyloxy)naphthalene-2-carboxylic acid ethyl ester

: cis-3-[2-(3,4,5-trimethoxy-phenyl)-vinyl]-naphthalen-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1: LiAlH₄ / tetrahydrofuran / 2.5 h / 0 - 20 °C

2: 370 mg / MnO₂ / CCl₄ / 2 h / 20 °C

3: NaH / tetrahydrofuran / 24 h / 20 °C

4: 220 mg / tetrabutylammonium fluoride / CH₂Cl₂ / 1 h / 20 °C

With manganese(IV) oxide; lithium aluminium tetrahydride; tetrabutyl ammonium fluoride; sodium hydride; In tetrahydrofuran; tetrachloromethane; dichloromethane;
DOI:10.1021/jm0510732

Reference yield:

: 894779-44-3
4-(tert-butyldimethylsilanyloxy)naphthalene-2-carboxylic acid ethyl ester

: trans-3-[2-(3,4,5-trimethoxy-phenyl)-vinyl]-naphthalen-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1: LiAlH₄ / tetrahydrofuran / 2.5 h / 0 - 20 °C

2: 370 mg / MnO₂ / CCl₄ / 2 h / 20 °C

3: NaH / tetrahydrofuran / 24 h / 20 °C

4: 270 mg / tetrabutylammonium fluoride / CH₂Cl₂ / 1 h / 20 °C

With manganese(IV) oxide; lithium aluminium tetrahydride; tetrabutyl ammonium fluoride; sodium hydride; In tetrahydrofuran; tetrachloromethane; dichloromethane;
DOI:10.1021/jm0510732