2-(1H-Benzo[d]imidazol-2-yl)-4-bromoaniline

Base Information

Chemical Name:2-(1H-Benzo[d]imidazol-2-yl)-4-bromoaniline
CAS No.:77123-67-2
Molecular Formula:C13H10BrN3
Molecular Weight:288.14
Hs Code.:2933990090
DSSTox Substance ID:DTXSID90506905
Wikidata:Q82362873
Mol file:77123-67-2.mol

Synonyms:2-(1H-Benzo[d]imidazol-2-yl)-4-bromoaniline;77123-67-2;2-(1H-benzimidazol-2-yl)-4-bromoaniline;2-(1H-1,3-BENZODIAZOL-2-YL)-4-BROMOANILINE;DTXSID90506905;AKOS008967322

Suppliers and Price of 2-(1H-Benzo[d]imidazol-2-yl)-4-bromoaniline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
2-(1H-Benzo[d]imidazol-2-yl)-4-bromoaniline 95+%
1g
$ 581.00

Chemenu
2-(1H-benzo[d]imidazol-2-yl)-4-bromoaniline 95%
1g
$ 549.00

American Custom Chemicals Corporation
2-(1H-BENZIMIDAZOL-2-YL)-4-BROMOBENZENAMINE 95.00%
5MG
$ 497.53

Alichem
2-(1H-Benzo[d]imidazol-2-yl)-4-bromoaniline
1g
$ 502.44

Total 5 raw suppliers

Chemical Property of 2-(1H-Benzo[d]imidazol-2-yl)-4-bromoaniline

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Melting Point:236-239 °C
Boiling Point:489.676°C at 760 mmHg
PKA:11.22±0.10(Predicted)
Flash Point:249.947°C
PSA：54.70000
Density:1.611g/cm³
LogP:4.15580
Storage Temp.:2-8°C
XLogP3:2.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:287.00581
Heavy Atom Count:17
Complexity:273

Purity/Quality:

99% ^*data from raw suppliers

2-(1H-Benzo[d]imidazol-2-yl)-4-bromoaniline 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C2C(=C1)NC(=N2)C3=C(C=CC(=C3)Br)N

Technology Process of 2-(1H-Benzo[d]imidazol-2-yl)-4-bromoaniline

There total 3 articles about 2-(1H-Benzo[d]imidazol-2-yl)-4-bromoaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.6%

: 5805-39-0
2-(aminophenyl)benzimidazole

: 77123-67-2
2-(1H-benzo[d]imidazol-2-yl)-4-bromoaniline

Guidance literature:: With bromine; In acetic acid; 1.) 0 deg C, 2.) 25 deg C, 30 min;
DOI:10.1021/jo00324a015

Reference yield:

: 66416-72-6
4-bromo-2-iodoaniline

: 77123-67-2
2-(1H-benzo[d]imidazol-2-yl)-4-bromoaniline

Guidance literature:: Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; cesium acetate / tetrahydrofuran / 16 h / 60 °C

2: acetic acid / 3 h / 100 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; cesium acetate; acetic acid; In tetrahydrofuran;
DOI:10.1021/acscatal.7b03000

Reference yield:

: 87-48-9
5-Bromo-1H-indole-2,3-dione

: 77123-67-2
2-(1H-benzo[d]imidazol-2-yl)-4-bromoaniline

Guidance literature:: Multi-step reaction with 2 steps

1: 3-chloro-benzenecarboperoxoic acid; acetic acid / 4 h / 20 °C

2: toluene / 12 h / Reflux

With acetic acid; 3-chloro-benzenecarboperoxoic acid; In toluene;
DOI:10.1016/j.bioorg.2020.103774