2-O,3-O:5-O,6-O-Diisopropylidene-1-deoxy-D-mannofuranose

Base Information

Chemical Name:2-O,3-O:5-O,6-O-Diisopropylidene-1-deoxy-D-mannofuranose
CAS No.:24807-77-0
Molecular Formula:C₁₂H₂₀O₅
Molecular Weight:244.288
Hs Code.:
Mol file:24807-77-0.mol

Synonyms:1,4-Anhydro-2-O,3-O:5-O,6-O-diisopropylidene-D-mannitol;2-O,3-O:5-O,6-O-Diisopropylidene-1-deoxy-D-mannofuranose

Suppliers and Price of 2-O,3-O:5-O,6-O-Diisopropylidene-1-deoxy-D-mannofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 2-O,3-O:5-O,6-O-Diisopropylidene-1-deoxy-D-mannofuranose

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-O,3-O:5-O,6-O-Diisopropylidene-1-deoxy-D-mannofuranose

There total 1 articles about 2-O,3-O:5-O,6-O-Diisopropylidene-1-deoxy-D-mannofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 96-36-6,868-85-9
methyl phosphite

: 98-59-9
p-toluenesulfonyl chloride

: 14131-84-1
2,3:5,6-di-O-isopropylidene-α-D-mannofuranose

: (1S)-2,3;5,6-Di-O-isopropyliden-1-methylphosphono-1-O-tosyl-D-mannit-δ-phoston

: (1R)-2,3;5,6-Di-O-isopropyliden-1-methylphosphono-1-O-tosyl-D-mannit-δ-phoston

: 93222-05-0
1,4-Anhydro-2,3-O-isopropyliden-5,6-di-O-tosyl-D-mannit

: 24807-77-0
1,4-Anhydro-2,3;5,6-di-O-isopropyliden-D-mannit

Guidance literature:: With pyridine; sodium methylate; Yield given. Multistep reaction. Yields of byproduct given; 2.) chloroform, room temp., 15 h;

Reference yield: 98.0%

: 7677-24-9
trimethylsilyl cyanide

: benzylammonium formate

: 24807-77-0
1,4-Anhydro-2,3;5,6-di-O-isopropyliden-D-mannit

: 1-N-benzylamino-1-C-cyano-1-deoxy-2,3:5,6-di-O-isopropylidene-D-mannose

Guidance literature:: benzylammonium formate; 1,4-Anhydro-2,3;5,6-di-O-isopropyliden-D-mannit; With titanium(IV) isopropylate; In methanol; at 20 ℃;

trimethylsilyl cyanide; In methanol; for 5h; optical yield given as %de; stereoselective reaction;
DOI:10.1016/j.tet.2009.01.108

Reference yield:

: 24807-77-0
1,4-Anhydro-2,3;5,6-di-O-isopropyliden-D-mannit

: 93222-05-0
1,4-Anhydro-2,3-O-isopropyliden-5,6-di-O-tosyl-D-mannit

Guidance literature:: Multi-step reaction with 2 steps

1: aqueous acetic acid

2: pyridine

With pyridine; acetic acid;
DOI:10.1039/jr9510000680