Methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyraNAside

Base Information

• Chemical Name: Methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyraNAside
• CAS No.: 19488-61-0
• Molecular Formula: C35H38O6
• Molecular Weight: 554.683
• Mol file: 19488-61-0.mol

Synonyms:Methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyraNAside;Methyl 2,3,4,6-tetrakis-O-(phenylmethyl)-beta-D-glucopyranoside

Chemical Property of Methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyraNAside

Chemical Property:

• PSA: 55.38000
• LogP: 6.33070

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyraNAside

There total 197 articles about Methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyraNAside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzyl bromide (100-39-0) + (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol (617-04-9) → (2R,3R,4S,5S,6S)-3,4,5-tris(benzyloxy)-2-((benzyloxy)methyl)-6-methoxytetrahydro-2H-pyran (3879-79-6,17791-37-6,19488-61-0,53008-63-2,69237-94-1,69237-95-2,71526-33-5,83462-67-3,84799-77-9,103421-29-0,103421-30-3,139241-42-2,61330-62-9)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; sodium hydride; In N,N-dimethyl-formamide; at 0 - 80 ℃;

DOI:10.1021/jo0478609

Reference yield: 100.0%

benzyl bromide (100-39-0) + methyl-alpha-D-glucopyranoside (97-30-3) → methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside (3879-79-6,17791-37-6,19488-61-0,53008-63-2,61330-62-9,69237-94-1,69237-95-2,71526-33-5,83462-67-3,84799-77-9,103421-29-0,103421-30-3,139241-42-2)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; at 20 ℃; for 2.5h;

DOI:10.1002/1521-3773(20000717)39:14<2466::AID-ANIE2466>3.0.CO;2-U

Reference yield: 98.1%

benzyl chloride (100-44-7) + methyl-alpha-D-glucopyranoside (97-30-3) → methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside (3879-79-6,17791-37-6,19488-61-0,53008-63-2,61330-62-9,69237-94-1,69237-95-2,71526-33-5,83462-67-3,84799-77-9,103421-29-0,103421-30-3,139241-42-2)

Guidance literature:

With sodium hydride; In toluene; paraffin oil; at 90 - 95 ℃; Temperature;

upstream raw materials:

methanol

phenyl 2,3,4,5-tetra-O-benzyl-1-thio-β-D-glucopyranoside

2,3,4,6-tetra-O-benzyl-D-glucopyranose

S-1-(1'-phenyl-1H-tetrazolyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranose

Downstream raw materials:

methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside

1-O-acetyl-2,3,4,6-tetra-O-benzyl-D-glucopyranose

2,3,4,6-tetra-O-benzyl-D-glucopyranose

2,3,4,6-tetra-O-benzyl-D-glucopyranoside