(1,5-Cyclooctadiene)bis(triMethylsilylMethyl)palladiuM(II)

Base Information

• Chemical Name: (1,5-Cyclooctadiene)bis(triMethylsilylMethyl)palladiuM(II)
• CAS No.: 225931-80-6
• Molecular Formula: C16H34PdSi2
• Molecular Weight: 389.037
• Mol file: 225931-80-6.mol

Synonyms:(1,5-Cyclooctadiene)bis(triMethylsilylMethyl)palladiuM(II)

Chemical Property of (1,5-Cyclooctadiene)bis(triMethylsilylMethyl)palladiuM(II)

Chemical Property:

• PSA: 0.00000
• LogP: 5.34940
• Storage Temp.: ?20°C
• Sensitive.: air sensitive, store cold

Purity/Quality:

97% ^*data from raw suppliers

Bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II), 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Novel Pd complex for synthesis of allylsilanes via the Silyl-Heck reaction and aryl fluorides.

Technology Process of (1,5-Cyclooctadiene)bis(triMethylsilylMethyl)palladiuM(II)

There total 3 articles about (1,5-Cyclooctadiene)bis(triMethylsilylMethyl)palladiuM(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) + (trimethylsilyl)methylmagnesium chloride (13170-43-9) → bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II) (225931-80-6)

Guidance literature:

In diethyl ether; at -25 ℃; for 1.5h; Inert atmosphere;

DOI:10.1021/acs.orglett.9b01532

Reference yield: 80.0%

dichloro(cycloocta-1,5-diene)palladium (II) (12107-56-1) + (trimethylsilyl)methylmagnesium chloride (13170-43-9) → bis(trimethylsilylmethyl)(cycloocta-1,5-diene)palladium(II) (225931-80-6)

Guidance literature:

In diethyl ether; N2-atmosphere; stirring Pd-complex with excess of Grignard reagent at -78°C, then at -10°C for 30 min; solvent removal (vac., < -10°C), extn. into hexane, filtration, evapn. (vac.), extn. into Me2CO, filtration, concn., crystn. (-30°C), filtration, drying (vac.); elem. anal.;

DOI:10.1016/S0022-328X(98)01071-7

Reference yield: 69.0%

dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) + Chloromethyltrimethylsilane (2344-80-1) → bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II) (225931-80-6)

Guidance literature:

Chloromethyltrimethylsilane; With magnesium; In diethyl ether;

dichloro(1,5-cyclooctadiene)palladium(II); In diethyl ether; at 0 ℃; Inert atmosphere;

DOI:10.1021/acs.organomet.6b00893

upstream raw materials:

dichloro(cycloocta-1,5-diene)palladium (II)

(trimethylsilyl)methylmagnesium chloride

dichloro(1,5-cyclooctadiene)palladium(II)

Chloromethyltrimethylsilane

Downstream raw materials:

bis(trimethylsilylmethyl)(bis-1,3-(diphenylphosphino)propane)palladium(II)