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Chloromethyltrimethylsilane

Base Information Edit
  • Chemical Name:Chloromethyltrimethylsilane
  • CAS No.:2344-80-1
  • Deprecated CAS:61696-01-3
  • Molecular Formula:C4H11ClSi
  • Molecular Weight:122.67
  • Hs Code.:29310095
  • European Community (EC) Number:219-058-5
  • DSSTox Substance ID:DTXSID1062330
  • Nikkaji Number:J47.467C
  • Wikipedia:(Trimethylsilyl)methyl_chloride
  • Wikidata:Q18212182
  • Mol file:2344-80-1.mol
Chloromethyltrimethylsilane

Synonyms:Chloromethyltrimethylsilane;2344-80-1;(Chloromethyl)trimethylsilane;Silane, (chloromethyl)trimethyl-;(Trimethylsilyl)methyl chloride;chloromethyl(trimethyl)silane;C4H11ClSi;(CH3)3SiCH2Cl;chloromethyl-trimethyl-silane;EINECS 219-058-5;EC 219-058-5;MFCD00000878;TMCMS;trimethylchloromethylsilane;trimethylsilylmethylchloride;chloromethyl-trimethylsilane;chloromethyltrimethyl-silane;Chloromethyl trimethylsilane;SCHEMBL6686;trimethylsilylmethyl chloride;chloromethyl-trimethyl silane;DTXSID1062330;(Chloromethyl)trimethylsilane, 98%;AMY39317;CC3285;AKOS000121082;FT-0604888;EN300-23990;I11290;S04425;A816721;J-015109;J-520037;Q63398400;F0001-0812;(Chloromethyl)trimethylsilane, produced by Wacker Chemie AG, Burghausen, Germany

Suppliers and Price of Chloromethyltrimethylsilane
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • Usbiological
  • Chloromethyl trimethylsilane
  • 25g
  • $ 389.00
  • TRC
  • (Chloromethyl)trimethylsilane
  • 5g
  • $ 50.00
  • TCI Chemical
  • (Chloromethyl)trimethylsilane >98.0%(GC)
  • 250mL
  • $ 352.00
  • TCI Chemical
  • (Chloromethyl)trimethylsilane >98.0%(GC)
  • 25mL
  • $ 78.00
  • TCI Chemical
  • (Chloromethyl)trimethylsilane >98.0%(GC)
  • 100mL
  • $ 176.00
  • SynQuest Laboratories
  • (Chloromethyl)trimethylsilane
  • 1 g
  • $ 16.00
  • SynQuest Laboratories
  • (Chloromethyl)trimethylsilane
  • 25 g
  • $ 96.00
  • SynQuest Laboratories
  • (Chloromethyl)trimethylsilane
  • 100 g
  • $ 208.00
  • Sigma-Aldrich
  • (Chloromethyl)trimethylsilane 98%
  • 100ml
  • $ 207.00
  • Sigma-Aldrich
  • (Chloromethyl)trimethylsilane 98%
  • 4x25ml
  • $ 197.00
Total 81 raw suppliers
Chemical Property of Chloromethyltrimethylsilane Edit
Chemical Property:
  • Appearance/Colour:clear colorless liquid 
  • Vapor Pressure:~25 mm Hg ( 20 °C) 
  • Melting Point:< 0 °C 
  • Refractive Index:n20/D 1.418(lit.)  
  • Boiling Point:96 °C at 760 mmHg 
  • Flash Point:27°F 
  • PSA:0.00000 
  • Density:0.865 g/cm3 
  • LogP:2.52090 
  • Storage Temp.:Flammables area 
  • Sensitive.:Moisture Sensitive 
  • Water Solubility.:insoluble 
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:0
  • Rotatable Bond Count:1
  • Exact Mass:122.0318546
  • Heavy Atom Count:6
  • Complexity:37.3
Purity/Quality:

99.9% *data from raw suppliers

Chloromethyl trimethylsilane *data from reagent suppliers

Safty Information:
  • Pictogram(s): FlammableF,IrritantXi,Corrosive
  • Hazard Codes:F,Xi,C 
  • Statements: 11-36/37/38-34 
  • Safety Statements: 16-26-36-29-37/39-33 
MSDS Files:

SDS file from LookChem

Useful:
  • Canonical SMILES:C[Si](C)(C)CCl
  • Uses (Chloromethyl)trimethylsilane is used for Wittig reaction and building blocks. (Chloromethyl)trimethylsilane can be treated with aldehydes or ketones in the presence of triphenylphosphine to synthesize terminal alkenes. It can also be used in the preparation of a reagent, trimethylsilylmethyl magnesium chloride, commonly used in Peterson methylenation.
Technology Process of Chloromethyltrimethylsilane

There total 24 articles about Chloromethyltrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With methylmagnesium bromide; In not given;
DOI:10.1021/ja01200a043
Guidance literature:
In neat (no solvent, gas phase); vapor phase chlorination at temp. of boiling benzene;;
DOI:10.1021/ja01148a542
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