6,6'-Biquinoline

Base Information

• Chemical Name: 6,6'-Biquinoline
• CAS No.: 612-79-3
• Molecular Formula: C18H12N2
• Molecular Weight: 256.307
• DSSTox Substance ID: DTXSID10347372
• Nikkaji Number: J134.709H
• Wikidata: Q63392284
• ChEMBL ID: CHEMBL1489335
• Mol file: 612-79-3.mol

Synonyms:6,6'-Biquinoline;612-79-3;6-quinolin-6-ylquinoline;[6,6']Biquinolinyl;6-(quinolin-6-yl)quinoline;Cambridge id 5132257;Oprea1_710183;Oprea1_746069;SCHEMBL30743;MLS001204757;IFLab1_001491;CHEMBL1489335;DTXSID10347372;HMS1416D17;HMS2815H18;CCG-15187;AKOS000677855;SMR000515777;EN300-235822;SR-01000390874;SR-01000390874-1;BRD-K58675002-001-13-6;Q63392284;F0405-0036

Chemical Property of 6,6'-Biquinoline

Chemical Property:

• PSA: 25.78000
• LogP: 4.45000
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 256.100048391
• Heavy Atom Count: 20
• Complexity: 297

Purity/Quality:

98%min ^*data from raw suppliers

6,6'-Biquinoline 95%+ ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C=CC(=C2)C3=CC4=C(C=C3)N=CC=C4)N=C1

Technology Process of 6,6'-Biquinoline

There total 2 articles about 6,6'-Biquinoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Azobenzene (1227476-15-4) → quinoline (91-22-5) + 6,6'-biquinoline (612-79-3)

Guidance literature:

With sulfuric acid; orthoarsenic acid; glycerol;

DOI:10.1021/ja01373a030

Reference yield:

sulfuric acid (7664-93-9) + orthoarsenic acid (7778-39-4,121471-47-4,1327-52-2) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) + trans-azobenzene (17082-12-1) → quinoline (91-22-5) + 6,6'-biquinoline (612-79-3)

Guidance literature:

at 195 ℃;

DOI:10.1021/ja01373a030

Reference yield: 84.0%

6,6'-biquinoline (612-79-3) + benzyl bromide (100-39-0) → N,N-dibenzyl-6,6'-biquinolinium dibromide

Guidance literature:

In acetonitrile;

DOI:10.1080/10587250008023831

upstream raw materials:

Azobenzene

sulfuric acid

orthoarsenic acid

glycerol

Downstream raw materials:

1,1'-dibenzoyl-1,2,1',2'-tetrahydro-[6,6']biquinolyl-2,2'-dicarbonitrile