[S,Z,(-)]-12-Hydroxy-9-octadecenoic acid methyl ester

Base Information

• Chemical Name: [S,Z,(-)]-12-Hydroxy-9-octadecenoic acid methyl ester
• CAS No.: 84799-82-6
• Molecular Formula: C19H36O3
• Molecular Weight: 312.493
• Hs Code.: 2918199090
• Mol file: 84799-82-6.mol

Synonyms:(-)-Ricinoleic acid methyl;[S,Z,(-)]-12-Hydroxy-9-octadecenoic acid methyl ester

Chemical Property of [S,Z,(-)]-12-Hydroxy-9-octadecenoic acid methyl ester

Chemical Property:

• PSA: 46.53000
• LogP: 5.16770

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [S,Z,(-)]-12-Hydroxy-9-octadecenoic acid methyl ester

There total 6 articles about [S,Z,(-)]-12-Hydroxy-9-octadecenoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

C58H106O9 → methyl ricinoleate (141-24-2,7706-01-6,23224-20-6,41989-07-5,67529-83-3,84799-82-6,84799-83-7,127062-53-7,127062-89-9)

Guidance literature:

In methanol;

DOI:10.1007/s10600-017-1959-6

Reference yield: 30.0%

Isopropenyl acetate (108-22-5) + methyl ricinoleate (41989-07-5) → [R-(Z)]-12-(acetyloxy)-9-octadecenoic acid methyl ester (140-03-4) + (Z)-(S)-12-hydroxyoctadec-9-enoic acid methyl ester (84799-82-6)

Guidance literature:

With Candida cylindrica lipase; In hexane; for 12h; Ambient temperature;

DOI:10.1080/00397919908086253

Reference yield:

heptanal (111-71-7) + Methyl 10-undecenoate (111-81-9) → methyl ricinoleate (23224-20-6,141-24-2,7706-01-6,41989-07-5,67529-83-3,84799-82-6,84799-83-7,127062-53-7,127062-89-9)

Guidance literature:

With aluminium trichloride;

DOI:10.1002/ejoc.200500701

upstream raw materials:

methanol

Ricinoleic acid

heptanal

Methyl 10-undecenoate

Downstream raw materials:

azelaic acid

heptanal

Methyl 10-undecenoate

octadec-9-ene-1,12-diol

Refernces

• 1、 Biermann, Ursula,Luetzen, Arne,Metzger, Juergen O.. "Synthesis of enantiomerically pure 2,3,4,6-tetrasubstituted tetrahydropyrans by Prins-type cyclization of methyl ricinoleate and aldehydes". . p. 2631 - 2637. Retrieved 2007/10/03.
• 2、 Blum,Sarel. "Synthetic and mass spectral study of bis ritter adducts from some dienoic fatty acids.". . p. 3121 - 3125. Retrieved 2007/10/05.