methyl 2,4-dimethoxy-6-<1'-(p-tolylsulfenyl)-5'-(p-tolylsulfonyl)pentyl>benzoate

Base Information

Chemical Name:methyl 2,4-dimethoxy-6-<1'-(p-tolylsulfenyl)-5'-(p-tolylsulfonyl)pentyl>benzoate
CAS No.:133042-99-6
Molecular Formula:C₂₉H₃₄O₆S₂
Molecular Weight:542.717
Hs Code.:

Synonyms:methyl 2,4-dimethoxy-6-<1'-(p-tolylsulfenyl)-5'-(p-tolylsulfonyl)pentyl>benzoate

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Chemical Property of methyl 2,4-dimethoxy-6-<1'-(p-tolylsulfenyl)-5'-(p-tolylsulfonyl)pentyl>benzoate

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Technology Process of methyl 2,4-dimethoxy-6-<1'-(p-tolylsulfenyl)-5'-(p-tolylsulfonyl)pentyl>benzoate

There total 4 articles about methyl 2,4-dimethoxy-6-<1'-(p-tolylsulfenyl)-5'-(p-tolylsulfonyl)pentyl>benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 17482-29-0
4-hydroxybutyl p-tolyl sulfone

: 133042-99-6
methyl 2,4-dimethoxy-6-<1'-(p-tolylsulfenyl)-5'-(p-tolylsulfonyl)pentyl>benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / triphenylphosphine, imidazole, iodine / toluene / 0.17 h / Ambient temperature

2: 1.) lithium hexamethyldisilazide 2.) HMPA / 1.) THF, -78 deg C, 15 min 2.) THF, -78 deg C, 15 min

With 1H-imidazole; N,N,N,N,N,N-hexamethylphosphoric triamide; iodine; triphenylphosphine; lithium hexamethyldisilazane; In toluene;
DOI:10.1021/jo00007a015

Reference yield:

: 133042-97-4
methyl 4-(p-tolylsulfonyl)butanoate

: 133042-99-6
methyl 2,4-dimethoxy-6-<1'-(p-tolylsulfenyl)-5'-(p-tolylsulfonyl)pentyl>benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / lithium aluminum hydride / tetrahydrofuran / 0.25 h / 0 °C

2: 82 percent / triphenylphosphine, imidazole, iodine / toluene / 0.17 h / Ambient temperature

3: 1.) lithium hexamethyldisilazide 2.) HMPA / 1.) THF, -78 deg C, 15 min 2.) THF, -78 deg C, 15 min

With 1H-imidazole; N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; iodine; triphenylphosphine; lithium hexamethyldisilazane; In tetrahydrofuran; toluene;
DOI:10.1021/jo00007a015

Reference yield:

: 130877-76-8
methyl 2,4-dimethoxy-6-(p-tolylsulfinyl) methyl benzoate

: 133042-99-6
methyl 2,4-dimethoxy-6-<1'-(p-tolylsulfenyl)-5'-(p-tolylsulfonyl)pentyl>benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / sodium iodide, BF₃*Et₂O / acetonitrile / 0.5 h / 0 °C

2: 1.) lithium hexamethyldisilazide 2.) HMPA / 1.) THF, -78 deg C, 15 min 2.) THF, -78 deg C, 15 min

With N,N,N,N,N,N-hexamethylphosphoric triamide; boron trifluoride diethyl etherate; sodium iodide; lithium hexamethyldisilazane; In acetonitrile;
DOI:10.1021/jo00007a015