17482-29-0Relevant academic research and scientific papers
A versatile approach to cyclic ethers. Synthesis of disubstituted oxepanes and oxocanes
Teresa Mujica,Afonso, Maria M.,Galindo, Antonio,Antonio Palenzuela
, p. 3401 - 3404 (2007/10/02)
A synthetic sequence for the preparation of α,α'-disubstituted cyclic ethers of various ring sizes and either relative stereochemistry (cis or trans) is presented. It is based on the hetero Diels Alder reaction of a monoactivated diene and an aldehyde, yi
Remote Participation during Photooxidation at Sulfur. Eidence for Sulfurane Intermediates
Clennan, E. L.,Yang, Kang
, p. 4477 - 4487 (2007/10/02)
The photooxidations of geminally substituted γ-hydroxy sulfides results in formation of unusual oxidative elimination products.Detailed spectral data and the independent synthesis of a close analogue provide compelling evidence for the structures of these
Asymmetric Synthesis of (S)-Zearalenone Dimethyl Ether, an Orsellinic Acid Type Macrolide
Solladie, Guy,Maestro, M. Carmen,Rubio, Almudena,Pedregal, Concepcion,Carreno, M. Carmen,Ruano, Jose L. Garcia
, p. 2317 - 2322 (2007/10/02)
The synthesis of (S)-zearalenone dimethyl ether is described.The chiral part of the molecule was obtained by asymmetric synthesis monitored by a chiral sulfoxide group and introduced in the very last steps of the synthesis.
A new method for the stereocontrolled synthesis of silyl dienol ethers using (naphtalene) chromium tricarbonyl catalyzed isomerization
Sodeoka, Mikiko,Yamada, Hiroyoshi,Shibasaki, Masakatsu
, p. 4906 - 4911 (2007/10/02)
Various tert-butyldimethylsilyl dienol ethers of type 4 were synthesized in a highly stereoselective manner for the first time. Treatment of (1Z)-1-[[(tert-butyldimethylsilyl)oxy] methyl] butadiene derivatives 1 with 20 mol % of (naphthalene) Cr(CO)3
