4C₆H₁₈NSi₂^(1-)*Co₂⁽⁴⁺⁾

Base Information

• Chemical Name: 4C₆H₁₈NSi₂^(1-)*Co₂⁽⁴⁺⁾
• CAS No.: 93280-44-5
• Molecular Formula: 4C₆H₁₈NSi₂*Co₂
• Molecular Weight: 759.533
• Mol file: 93280-44-5.mol

Synonyms:4C₆H₁₈NSi₂^(1-)*Co₂⁽⁴⁺⁾

Chemical Property of 4C₆H₁₈NSi₂^(1-)*Co₂⁽⁴⁺⁾

Chemical Property:

Purity/Quality:

99%+ ^*data from raw suppliers

Bis{[μ-[di(trimethylsilyl)amide]}bis{[di(trimethylsilyl)amide]}dicobalt(II), 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: Starting material for the synthesis of a variety of cobalt amines and alkoxides.

Technology Process of 4C₆H₁₈NSi₂^(1-)*Co₂⁽⁴⁺⁾

There total 1 articles about 4C₆H₁₈NSi₂^(1-)*Co₂⁽⁴⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → [Co{N(SiMe3)2}2]2 (93280-44-5)

Guidance literature:

1,1,1,3,3,3-hexamethyl-disilazane; With n-butyllithium; In diethyl ether; hexane; at 20 ℃; for 16h; Cooling with ice; Inert atmosphere;

cobalt(II) chloride; In diethyl ether; hexane; at 35 ℃; for 12h; Cooling with liquid nitrogen; Inert atmosphere;

DOI:10.1021/ic402019w

Reference yield: 78.0%

[Co{N(SiMe3)2}2]2 (93280-44-5) + 2,2″,4,4″,6,6″-hexamethyl-m-terphenol (214491-83-5) → Co(OC6H3-2,6(C6H2-2,4,6-Me3)2)2

Guidance literature:

at 85 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1021/ic403098p

Reference yield: 68.0%

[Co{N(SiMe3)2}2]2 (93280-44-5) + tricyclohexylphosphine (2622-14-2) → [Co{N(SiMe3)2}2(Pcyclohexyl3)] (1547408-78-5)

Guidance literature:

In n-heptane; Heating; Inert atmosphere;

DOI:10.1021/ic401677j

upstream raw materials:

1,1,1,3,3,3-hexamethyl-disilazane

cobalt(II) chloride

Downstream raw materials:

Co{OC(4-MeC₆H₄)3}2(THF)2

Co(OC(C₆H₅)3)2(C₄H₈O)2

[Co{N(SiMe₃)₂}₂(Pcyclohexyl₃)]