2-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-pentafluorophenyl-ethylideneamine

Base Information

• Chemical Name: 2-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-pentafluorophenyl-ethylideneamine
• CAS No.: 180304-58-9
• Molecular Formula: C₂₀H₁₇F₁₀NOSi
• Molecular Weight: 505.431
• Mol file: 180304-58-9.mol

Synonyms:2-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-pentafluorophenyl-ethylideneamine

Chemical Property of 2-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-pentafluorophenyl-ethylideneamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-pentafluorophenyl-ethylideneamine

There total 3 articles about 2-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-pentafluorophenyl-ethylideneamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

perfluorobenzaldehyde (653-37-2) → 2-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-pentafluorophenyl-ethylideneamine (180304-58-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 85 percent / ZnBr₂ / acetonitrile

2: 1.) n-BuLi / 1.) ether, 2.) ether, -85 deg C, 5 min

With n-butyllithium; zinc dibromide; In acetonitrile;

DOI:10.1016/0957-4166(96)00221-2

Reference yield:

tert-butyldimethylsilyl chloride (18162-48-6) → 2-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-pentafluorophenyl-ethylideneamine (180304-58-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 85 percent / ZnBr₂ / acetonitrile

2: 1.) n-BuLi / 1.) ether, 2.) ether, -85 deg C, 5 min

With n-butyllithium; zinc dibromide; In acetonitrile;

DOI:10.1016/0957-4166(96)00221-2

Reference yield:

bromopentafluorobenzene (344-04-7) + (+/-)-2-(tert-butyldimethylsiloxy)-2-(pentafluorophenyl)acetonitrile (180304-57-8) → 2-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-pentafluorophenyl-ethylideneamine (180304-58-9)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction; 1.) ether, 2.) ether, -85 deg C, 5 min;

DOI:10.1016/0957-4166(96)00221-2

upstream raw materials:

bromopentafluorobenzene

(+/-)-2-(tert-butyldimethylsiloxy)-2-(pentafluorophenyl)acetonitrile

perfluorobenzaldehyde

tert-butyldimethylsilyl chloride