1′-(diphenylphosphino)-1-hydroxymethylferrocene-borane (1/1)

Base Information

• Chemical Name: 1′-(diphenylphosphino)-1-hydroxymethylferrocene-borane (1/1)
• CAS No.: 1423762-44-0
• Molecular Formula: C₂₃H₂₄BFeOP
• Molecular Weight: 414.075
• Mol file: 1423762-44-0.mol

Synonyms:1′-(diphenylphosphino)-1-hydroxymethylferrocene-borane (1/1)

Chemical Property of 1′-(diphenylphosphino)-1-hydroxymethylferrocene-borane (1/1)

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 1′-(diphenylphosphino)-1-hydroxymethylferrocene-borane (1/1)

There total 4 articles about 1′-(diphenylphosphino)-1-hydroxymethylferrocene-borane (1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1′-(diphenylphosphino)ferrocene-1-carbaldehyde (124944-40-7) + borane tetrahydrofuran → fc-P(C6H5)2BH3 + 1′-(diphenylphosphino)-1-hydroxymethylferrocene-borane (1/1) (1423762-44-0)

Guidance literature:

In tetrahydrofuran; at 0 ℃; for 1.5h; Temperature;

DOI:10.1039/c2dt32511j

Reference yield: 91.0%

1′-(diphenylphosphino)ferrocene-1-carbaldehyde (124944-40-7) + dimethyl sulfide borane (13292-87-0) → 1′-(diphenylphosphino)-1-hydroxymethylferrocene-borane (1/1) (1423762-44-0)

Guidance literature:

In tetrahydrofuran; at 0 ℃;

DOI:10.1039/c2dt32511j

Reference yield: 89.0%

1′-(diphenylphosphino)ferrocene-1-carbaldehyde (386702-89-2) + borane tetrahydrofuran → 1′-(diphenylphosphino)-1-hydroxymethylferrocene-borane (1/1) (1423762-44-0)

Guidance literature:

With sodium tetrahydroborate; In tetrahydrofuran; at 0 ℃; for 1.5h;

DOI:10.1039/c2dt32511j

upstream raw materials:

1′-(diphenylphosphino)ferrocene-1-carbaldehyde

dimethyl sulfide borane

1′-(diphenylphosphino)ferrocene-1-carbaldehyde

Downstream raw materials:

1′-(diphenylphosphino)-1-(methoxymethyl)ferrocene-borane(1/1)

triethylenediamine*BH₃

1′-(diphenylphosphino)ferrocene-1-carbaldehyde