methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-oxododecanoate

Base Information

Chemical Name:methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-oxododecanoate
CAS No.:1250395-32-4
Molecular Formula:C₄₈H₇₄O₁₁Si₂
Molecular Weight:883.28
Hs Code.:

methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-oxododecanoate

Synonyms:methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-oxododecanoate

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Chemical Property of methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-oxododecanoate

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Technology Process of methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-oxododecanoate

There total 1 articles about methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-oxododecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1250395-31-3
methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-dodecenoate

: 1250395-32-4
methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-oxododecanoate

Guidance literature:: methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-dodecenoate; With pyridine; ozone; In methanol; dichloromethane; at -78 ℃;

With dimethylsulfide; In methanol; dichloromethane; at -78 - 20 ℃;
DOI:10.1002/anie.201002293

Reference yield: 64.5%

: 1133769-93-3
(4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one

: 1250395-32-4
methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-oxododecanoate

: 1250395-71-1
methyl (2S,3R,5S,7R,8R,9S,11S,15S,16Z,18R)-8-(tert-butyldimethylsilyloxy)-18-[(tertbutyldimethylsilyloxy)methyl]-5-(tert-butyldiphenylsilyloxy)-11-hydroxy-3,7-dimethoxy-9,15-bis(4-methoxyphenylmethoxy)-2-(methoxymethoxy)-10,10,16-trimethyl-13-oxo-16-icosenoate

Guidance literature:: (4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one; With dicyclohexylboron chloride; triethylamine; In diethyl ether; at -78 - -40 ℃; Inert atmosphere;

methyl (2S,3R,5S,7R,8R,9S)-8-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-9-(4-methoxybenzyloxy)-2-(methoxymethoxy)-10,10-dimethyl-11-oxododecanoate; In diethyl ether; at -78 - -20 ℃; Inert atmosphere;
DOI:10.1002/anie.201002293