(4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one

Base Information

Chemical Name:(4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one
CAS No.:1133769-93-3
Molecular Formula:C₂₅H₄₂O₄Si
Molecular Weight:434.692
Hs Code.:

Synonyms:(4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one

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Chemical Property of (4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one

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Technology Process of (4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one

There total 3 articles about (4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1133770-45-2
(1S,4R)(2Z)-1-[(4-methoxyphenyl)methoxy]-2-methyl-1-prop-2-enyl-4-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]hex-2-ene

: 1133769-93-3
(4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one

Guidance literature:: With oxygen; copper(II) acetate monohydrate; palladium dichloride; In water; N,N-dimethyl-formamide; at 20 ℃;

Reference yield: 45.0%

: 1250395-70-0
C₁₉H₂₈O₄

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1133769-93-3
(4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one

Guidance literature:: With dmap; triethylamine; In dichloromethane; for 12h;
DOI:10.1002/anie.201002293

Reference yield:

: 1250395-63-1
2-propenyl (2Z,5S,8R,6Z)-3-amino-8-[(tert-butyldimethylsilyloxy)methyl]-5-(4-methoxyphenylmethoxy)-6-methyl-2,6-decadienoate

: 1133769-93-3
(4S,7R)(5Z)-4-[(4-methoxyphenyl)methoxy]-5-methyl-7-[(1,1,2,2-tetramethyl-1-silapropoxy)methyl]non-5-en-2-one

: 1250395-70-0
C₁₉H₂₈O₄

Guidance literature:: 2-propenyl (2Z,5S,8R,6Z)-3-amino-8-[(tert-butyldimethylsilyloxy)methyl]-5-(4-methoxyphenylmethoxy)-6-methyl-2,6-decadienoate; With water; In tetrahydrofuran; isopropyl alcohol; for 22h; pH=3; aq. phosphate buffer;

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; formic acid; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at 20 ℃; for 12h;
DOI:10.1002/anie.201002293