1-<(6S,1R,2R)-8,8-dimethyl-4,7,9-trioxa-5-(phenylmethoxy)bicyclo<4.3.0>non-2-yloxy>-1,1,2,2-tetramethyl-1-silapropane

Base Information

Chemical Name:1-<(6S,1R,2R)-8,8-dimethyl-4,7,9-trioxa-5-(phenylmethoxy)bicyclo<4.3.0>non-2-yloxy>-1,1,2,2-tetramethyl-1-silapropane
CAS No.:184481-20-7
Molecular Formula:C₂₁H₃₄O₅Si
Molecular Weight:394.583
Hs Code.:

Synonyms:1-<(6S,1R,2R)-8,8-dimethyl-4,7,9-trioxa-5-(phenylmethoxy)bicyclo<4.3.0>non-2-yloxy>-1,1,2,2-tetramethyl-1-silapropane

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Chemical Property of 1-<(6S,1R,2R)-8,8-dimethyl-4,7,9-trioxa-5-(phenylmethoxy)bicyclo<4.3.0>non-2-yloxy>-1,1,2,2-tetramethyl-1-silapropane

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Technology Process of 1-<(6S,1R,2R)-8,8-dimethyl-4,7,9-trioxa-5-(phenylmethoxy)bicyclo<4.3.0>non-2-yloxy>-1,1,2,2-tetramethyl-1-silapropane

There total 5 articles about 1-<(6S,1R,2R)-8,8-dimethyl-4,7,9-trioxa-5-(phenylmethoxy)bicyclo<4.3.0>non-2-yloxy>-1,1,2,2-tetramethyl-1-silapropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 184481-19-4
(1S,6S,2R)-8,8-dimethyl-4,7,9-trioxa-5-(phenylmethoxy)bicyclo<4.3.0>nonan-2-ol

: 184481-20-7
1-<(6S,1R,2R)-8,8-dimethyl-4,7,9-trioxa-5-(phenylmethoxy)bicyclo<4.3.0>non-2-yloxy>-1,1,2,2-tetramethyl-1-silapropane

Guidance literature:: With 1H-imidazole;
DOI:10.1021/jo961619f

Reference yield:

: 87-72-9,608-45-7,608-46-8,608-47-9,2460-44-8,6748-95-4,6763-34-4,7261-26-9,7283-06-9,7283-07-0,7296-55-1,7296-56-2,7296-58-4,7296-59-5,7296-60-8,7296-61-9,7296-62-0,7322-30-7,10257-31-5,10257-32-6,10257-33-7,10257-34-8,10257-35-9,19982-83-3,20242-88-0,28697-53-2,36562-42-2,41546-41-2,89299-64-9,107655-34-5,115794-06-4,115794-07-5,130550-15-1,130606-21-2
D-lyxose

: 184481-20-7
1-<(6S,1R,2R)-8,8-dimethyl-4,7,9-trioxa-5-(phenylmethoxy)bicyclo<4.3.0>non-2-yloxy>-1,1,2,2-tetramethyl-1-silapropane

Guidance literature:: Multi-step reaction with 3 steps

1: p-TsOH*H₂O / 48 h / 60 °C

2: 90 percent / p-TsOH*H₂O / acetone / 24 h / Ambient temperature

3: 95 percent / imidazole / dimethylformamide / 2 h / Ambient temperature

With 1H-imidazole; toluene-4-sulfonic acid; In N,N-dimethyl-formamide; acetone;
DOI:10.1021/ja9826688

Reference yield:

: 184481-18-3
(5S,3R,4R)-2-(phenylmethoxy)perhydro-2H-pyran-3,4,5-triol

: 184481-20-7
1-<(6S,1R,2R)-8,8-dimethyl-4,7,9-trioxa-5-(phenylmethoxy)bicyclo<4.3.0>non-2-yloxy>-1,1,2,2-tetramethyl-1-silapropane

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / p-TsOH*H₂O / acetone / 24 h / Ambient temperature

2: 95 percent / imidazole / dimethylformamide / 2 h / Ambient temperature

With 1H-imidazole; toluene-4-sulfonic acid; In N,N-dimethyl-formamide; acetone;
DOI:10.1021/ja9826688