{[PhBP₃^iPr]}FeCl

Base Information

• Chemical Name: {[PhBP₃^iPr]}FeCl
• CAS No.: 579444-62-5
• Molecular Formula: C₂₇H₅₃BClFeP₃
• Molecular Weight: 572.75
• Mol file: 579444-62-5.mol

Synonyms:{[PhBP₃^iPr]}FeCl

Chemical Property of {[PhBP₃^iPr]}FeCl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of {[PhBP₃^iPr]}FeCl

There total 1 articles about {[PhBP₃^iPr]}FeCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

[tris(diisopropylphosphino)borate]thallium (579444-61-4) + iron(II) chloride → {[PhBP3iPr]}FeCl (579444-62-5)

Guidance literature:

In tetrahydrofuran; N2; addn. of THF soln. of the borate to stirring THF suspn. of FeCl2 at room temp., stirring for 2 h; filtration (Celite), evapn. to dryness in vac., dissolving the solid in benzene, filtration again, crystn. by slow evapn. of benzene soln.; elem. anal.;

DOI:10.1021/ic0343096

Reference yield: 98.0%

{[PhBP3iPr]}FeCl (579444-62-5) + carbon monoxide (201230-82-2) → [tris(diisopropylphosphino)borate]FeCl(carbon monoxide) (579444-67-0)

Guidance literature:

In benzene; sparging benzene soln. of the complex with CO at room temp. with stirring for 1 min, stirring for 0.5 h; evapn. to dryness in vac.; elem. anal.;

DOI:10.1021/ic0343096

Reference yield: 84.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + {[PhBP3iPr]}FeCl (579444-62-5) + nitrogen (7727-37-9) + magnesium (7439-95-4) → C6H5B(CH2P(C3H7)2)3FeN2(1-)*MgCl(C4H8O)2(1+)=C6H5B(CH2P(C3H7)2)3FeN2MgCl(C4H8O)2 (606927-86-0)

Guidance literature:

In tetrahydrofuran; THF-soln. under a blanket of N2 in the presence of Mg(0);

DOI:10.1021/ja036687f

upstream raw materials:

[tris(diisopropylphosphino)borate]thallium

Downstream raw materials:

C₆H₅B(CH₂P(C₃H₇)2)3FeN₂^(1-)*MgCl(C₄H₈O)2⁽¹⁺⁾=C₆H₅B(CH₂P(C₃H₇)2)3FeN₂MgCl(C₄H₈O)2

[tris(diisopropylphosphino)borate]FeCl(carbon monoxide)

[(C₆H₅B(CH₂P(CH(CH₃)2)2)3)Fe(H)(P(CH₃)3)]

[PhB(CH₂P(i-Pr)2)3]Fe(2,3:5,6-dibenzo-7-aza bicyclo[2.2.1]hepta-2,5-diene)

Refernces