Technology Process of Tl[PhB(CH2P(i)Pr2)3]
There total 1 articles about Tl[PhB(CH2P(i)Pr2)3] which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
TMEDA;
In
tetrahydrofuran; diethyl ether;
byproducts: Tl; N2; dropwise addn. of boron compd. dissolved in toluene to ether suspn. of organolithium compd. contg. 1 equiv.of TMEDA at -78°C, warmingto room temp. over 10 min, filtration, addn. of THF soln. of TlPF6; collecting the ppt. of glass frit, addn. of petroleum ether to the supernatant, cooling to -33°C, decantation, washing the solids with acetonitrile, recrystn. from toluene-petroleum ether (1:1 vol.) at -33°C; elem. anal.;
DOI:10.1021/ic0343096
- Guidance literature:
-
In
tetrahydrofuran;
byproducts: TlCl; under N2; Ni-complex was suspended in THF, THF soln. of Tl-complex was added dropwise over 10 min with stirring, stirred for 25 min; filtered, washed with benzene, concd. under reduced pressure, dissolved in benzene, filtered, lyophilized; elem. anal.;
DOI:10.1021/ic049936p
- Guidance literature:
-
In
tetrahydrofuran;
N2; addn. of THF soln. of the borate to stirring THF suspn. of FeCl2 at room temp., stirring for 2 h; filtration (Celite), evapn. to dryness in vac., dissolving the solid in benzene, filtration again, crystn. by slow evapn. of benzene soln.; elem. anal.;
DOI:10.1021/ic0343096
