thexyldimethylsilyl 3,6-di-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-2-deoxy-2-2-dimethylmaleimido-β-D-glucopyranoside

Base Information

Chemical Name:thexyldimethylsilyl 3,6-di-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-2-deoxy-2-2-dimethylmaleimido-β-D-glucopyranoside
CAS No.:303082-25-9
Molecular Formula:C₄₉H₅₇NO₉Si
Molecular Weight:832.078
Hs Code.:

Synonyms:thexyldimethylsilyl 3,6-di-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-2-deoxy-2-2-dimethylmaleimido-β-D-glucopyranoside

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Chemical Property of thexyldimethylsilyl 3,6-di-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-2-deoxy-2-2-dimethylmaleimido-β-D-glucopyranoside

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Technology Process of thexyldimethylsilyl 3,6-di-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-2-deoxy-2-2-dimethylmaleimido-β-D-glucopyranoside

There total 1 articles about thexyldimethylsilyl 3,6-di-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-2-deoxy-2-2-dimethylmaleimido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 28920-43-6
(fluorenylmethoxy)carbonyl chloride

: 303082-23-7
thexyldimethylsilyl 2-deoxy-2-(dimethylmaleoylimido)-3,6-di-O-benzyl-β-D-glucopyranoside

: 303082-25-9
thexyldimethylsilyl 3,6-di-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-2-deoxy-2-2-dimethylmaleimido-β-D-glucopyranoside

Guidance literature:: With dmap; In pyridine; at 20 ℃; for 8h;
DOI:10.1021/jo016018p

Reference yield: 86.0%

: 303082-25-9
thexyldimethylsilyl 3,6-di-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-2-deoxy-2-2-dimethylmaleimido-β-D-glucopyranoside

: 303082-27-1
O-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranose

Guidance literature:: With pyridine hydrogenfluoride; In tetrahydrofuran; at 20 ℃; for 2h;
DOI:10.1021/jo016018p

Reference yield:

: 303082-25-9
thexyldimethylsilyl 3,6-di-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-2-deoxy-2-2-dimethylmaleimido-β-D-glucopyranoside

: 303082-29-3
O-[3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyl]trichloroacetimidate

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / HF*pyridine / tetrahydrofuran / 2 h / 20 °C

2: 88 percent / NaH / CH₂Cl₂ / 0.25 h

With sodium hydride; pyridine hydrogenfluoride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo016018p