9-Fluorenylmethyl chloroformate

Base Information Edit

Chemical Name:9-Fluorenylmethyl chloroformate
CAS No.:28920-43-6
Molecular Formula:C15H11ClO2
Molecular Weight:258.704
Hs Code.:2915.90
European Community (EC) Number:249-313-6
UNII:9PLB0BTT90
DSSTox Substance ID:DTXSID10183116
Nikkaji Number:J311E
Wikipedia:Fluorenylmethyloxycarbonyl_chloride
Wikidata:Q827647
Mol file:28920-43-6.mol

Synonyms:1-(9-fluorenyl)methyl chloroformate;9-FLMC;9-fluorenylmethoxycarbonyl chloride;9-fluorenylmethyl chloroformate;9-fluorenylmethylchloroformate;FMOC-Cl

Suppliers and Price of 9-Fluorenylmethyl chloroformate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
Fmoc-Cl
50g
$ 395.00

TRC
9-FluorenylmethylChlorocarbonate
25g
$ 275.00

TRC
9-FluorenylmethylChlorocarbonate
100g
$ 640.00

TCI Chemical
9-Fluorenylmethyl Chloroformate [N-Protecting Agent for Peptides Research] >97.0%(HPLC)(T)
100g
$ 495.00

TCI Chemical
9-Fluorenylmethyl Chloroformate [N-Protecting Agent for Peptides Research] >97.0%(HPLC)(T)
25g
$ 165.00

TCI Chemical
9-Fluorenylmethyl Chloroformate [N-Protecting Agent for Peptides Research] >97.0%(HPLC)(T)
5g
$ 49.00

SynQuest Laboratories
(9H-Fluoren-9-yl)methyl chloroformate
25 g
$ 39.00

SynQuest Laboratories
(9H-Fluoren-9-yl)methyl chloroformate
100 g
$ 80.00

Soltec Ventures
(9-Fluorenylmethyl) chloroformate
1gm
$ 25.20

Soltec Ventures
(9-Fluorenylmethyl) chloroformate
5gm
$ 119.00

Total 197 raw suppliers

Chemical Property of 9-Fluorenylmethyl chloroformate Edit

Chemical Property:

Appearance/Colour:white to off-white powder
Vapor Pressure:2.06E-06mmHg at 25°C
Melting Point:62-64 °C(lit.)
Refractive Index:1.611
Boiling Point:393.9 °C at 760 mmHg
Flash Point:143.6 °C
PSA：26.30000
Density:1.288 g/cm³
LogP:4.17430
Storage Temp.:2-8°C
Sensitive.:Moisture Sensitive
Solubility.:dioxane: 0.1 g/mL, clear, colorless
XLogP3:4.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:258.0447573
Heavy Atom Count:18
Complexity:296

Purity/Quality:

≥98%,≥99%, ^*data from raw suppliers

Fmoc-Cl ^*data from reagent suppliers

Safty Information:

Pictogram(s): C,T
Hazard Codes:C,T
Statements: 34-20/21/22
Safety Statements: 26-36/37/39-45-27

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1=CC=C2C(=C1)C(C3=CC=CC=C32)COC(=O)Cl
Uses 9-Fluorenylmethyl chloroformate is an N-Protecting agent for peptides research and was used for the pre-column derivatization of the biogenic amines (BAs) cadaverine (Cad), histamine (Him), octopami ne (Ocp), phenylethylamine (Pea), putrescine (Put), spermidine (Spd), spermine (Spm), tyramine (Tym). 9-Fluorenylmethyl chloroformate can be used as N-protecting reagent for oligonucleotide and peptide syntheses. 9-Fluorenylmethyl chloroformate can act as reagent for the introduction of Fmoc-amino-protecting group, which is stable towards acids but is readily cleaved under mildly basic non-hydrolytic conditions.

Technology Process of 9-Fluorenylmethyl chloroformate

There total 8 articles about 9-Fluorenylmethyl chloroformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%