cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside

Base Information

• Chemical Name: cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside
• CAS No.: 240418-69-3
• Molecular Formula: C₁₆H₂₄O₅S
• Molecular Weight: 328.43
• Mol file: 240418-69-3.mol

Synonyms:cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside

Chemical Property of cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside

There total 2 articles about cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

Cyclohexanethiol (1569-69-3) + D-glucal triacetate (2873-29-2) → cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside (240418-69-3)

Guidance literature:

With samarium(III) trifluoromethanesulfonate; In acetonitrile; at 40 ℃; for 0.333333h;

DOI:10.1016/j.tet.2014.09.060

Reference yield:

Cyclohexanethiol (1569-69-3) + D-glucal triacetate (2873-29-2) → cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside (240418-69-3) + C16H24O5S

Guidance literature:

With ruthenium(III) chloride trihydrate; In acetonitrile; at -20 ℃; for 5h; Overall yield = 65 %; stereoselective reaction;

DOI:10.1016/j.tet.2013.09.061

upstream raw materials:

Cyclohexanethiol

D-glucal triacetate