1-Chlor-1-styryl-stannacyclohexan

Base Information

• Chemical Name: 1-Chlor-1-styryl-stannacyclohexan
• CAS No.: 74255-87-1
• Molecular Formula: C₁₃H₁₇ClSn
• Molecular Weight: 327.441
• Mol file: 74255-87-1.mol

Synonyms:1-Chlor-1-styryl-stannacyclohexan

Chemical Property of 1-Chlor-1-styryl-stannacyclohexan

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 1-Chlor-1-styryl-stannacyclohexan

There total 1 articles about 1-Chlor-1-styryl-stannacyclohexan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.9%

4-vinylbenzyl chloride (1073-67-2,24991-47-7) + Cl2Sn(CH2)5 (74255-85-9) + magnesium (7439-95-4) → 1-Chlor-1-styryl-stannacyclohexan (74255-87-1) + 1,1-di(p-styryl)stannacyclohexane (74255-86-0)

Guidance literature:

With t-butylcatechol; HCl; In diethyl ether; pentane; byproducts: MgCl2; (Ar); Grignard soln. from Mg and styryl chloride was dropped to soln. of tin compd. within 1-1,5 h, t-butylcatechol was added and mixt. stirredovernight; solvent was removed in vac., residue taken up in toluene and treated with dild. HCl (ice-cooling), org. phases were concd. and sepd. by chromy.(silica gel, PE/diethyl ether); elem. anal.;

DOI:10.1016/S0022-328X(00)93423-5

Reference yield: 91.0%

1-Chlor-1-styryl-stannacyclohexan (74255-87-1) + di-tert-butyl(trimethylsilyl)phosphane (42491-34-9) → chloro-trimethyl-silane (75-77-4) + 1-Di-t-butylphosphino-1-styryl-stannacyclohexan (74333-51-0)

Guidance literature:

In diethyl ether; toluene; addn. of equimolar amts. of Me3SiP(t-Bu)2 in toluene to satd. soln. of ((C5H10)Sn(CH2CHPh)Cl in ether, 1h, room temp., stirred, distn. under vac., under Ar; elem. anal.;

DOI:10.1016/S0022-328X(00)82878-8

upstream raw materials:

4-vinylbenzyl chloride

Cl₂Sn(CH₂)5

magnesium

Downstream raw materials:

chloro-trimethyl-silane

1-Di-t-butylphosphino-1-styryl-stannacyclohexan