[Re(CO)3(4'-phenyl-2,2':6',2''-terpyridine)Cl]

Base Information

• Chemical Name: [Re(CO)3(4'-phenyl-2,2':6',2''-terpyridine)Cl]
• CAS No.: 515125-29-8
• Molecular Formula: C₂₄H₁₅ClN₃O₃Re
• Molecular Weight: 615.061
• Mol file: 515125-29-8.mol

Synonyms:[Re(CO)3(4'-phenyl-2,2':6',2''-terpyridine)Cl]

Chemical Property of [Re(CO)3(4'-phenyl-2,2':6',2''-terpyridine)Cl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Re(CO)3(4'-phenyl-2,2':6',2''-terpyridine)Cl]

There total 1 articles about [Re(CO)3(4'-phenyl-2,2':6',2''-terpyridine)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-acetylpyridine (1122-62-9) + benzaldehyde (100-52-7) → [Re(CO)3(4'-phenyl-2,2':6',2''-terpyridine)Cl] (515125-29-8)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium hydroxide; ammonium hydroxide / ethanol / 24 h / 20 °C

2: acetonitrile / Reflux

With ammonium hydroxide; potassium hydroxide; In ethanol; acetonitrile;

DOI:10.1002/aoc.4611

Reference yield: 100.0%

[Re(CO)3(4'-phenyl-2,2':6',2''-terpyridine)Cl] (515125-29-8) → [Re(κ3N-4’-Ph-tpy)(CO)2Cl]

Guidance literature:

at 300 ℃; for 12h; under 7.50075E-05 Torr; Sealed tube;

DOI:10.1021/acs.inorgchem.0c02914

Reference yield: 72.0%

[Re(CO)3(4'-phenyl-2,2':6',2''-terpyridine)Cl] (515125-29-8) + silver trifluoromethanesulfonate (2923-28-6) + acetonitrile (75-05-8,26809-02-9) → [Re(CO)3(CH3CN)(4'-phenyl-2,2':6',2''-terpyridine)]CF3SO3 (515125-20-9)

Guidance literature:

In acetonitrile; byproducts: AgCl; the mixt. in acetonitrile was refluxed for 10 h (N2); the solvent was removed in vac., extd. with CH2Cl2, filtered, reduced invol., cold pentane was added, ppt. was filtered and dried in vac.; elem . anal.;

DOI:10.1039/b208211j

upstream raw materials:

2-acetylpyridine

benzaldehyde

Downstream raw materials:

[Re(CO)3(CH₃CN)(4'-phenyl-2,2':6',2''-terpyridine)]CF₃SO₃