((1R,2S,3S,4R,5S,6R)-2,3,4,5,6-Pentamethoxy-cyclohexyloxymethyl)-benzene

Base Information

Chemical Name:((1R,2S,3S,4R,5S,6R)-2,3,4,5,6-Pentamethoxy-cyclohexyloxymethyl)-benzene
CAS No.:117708-51-7
Molecular Formula:C₁₈H₂₈O₆
Molecular Weight:340.417
Hs Code.:

Synonyms:((1R,2S,3S,4R,5S,6R)-2,3,4,5,6-Pentamethoxy-cyclohexyloxymethyl)-benzene

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Chemical Property of ((1R,2S,3S,4R,5S,6R)-2,3,4,5,6-Pentamethoxy-cyclohexyloxymethyl)-benzene

Chemical Property:

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Technology Process of ((1R,2S,3S,4R,5S,6R)-2,3,4,5,6-Pentamethoxy-cyclohexyloxymethyl)-benzene

There total 8 articles about ((1R,2S,3S,4R,5S,6R)-2,3,4,5,6-Pentamethoxy-cyclohexyloxymethyl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6848-53-9
L-3,4:5.6-di-O-cyclohexylidene-2-O-methyl-(-)-chiro-inositol

: 117708-51-7
((1R,2S,3S,4R,5S,6R)-2,3,4,5,6-Pentamethoxy-cyclohexyloxymethyl)-benzene

Guidance literature:: Multi-step reaction with 7 steps

1: 100 percent / AcOH; H₂O / 4 h / 20 °C

2: 1.39 g / NaH / dimethylformamide / 20 °C

3: 0.96 g / TFA; H₂O / 20 °C

4: 320 mg / Bu₄NBr; (Bu₃Sn)2O / toluene / Heating

5: 162 mg / NaIO₄; K₂CO₃ / RuCl₃ / acetonitrile; CH₂Cl₂; H₂O / 20 °C

6: 122 mg / NaBH₄ / tetrahydrofuran; H₂O / 3 h / 20 °C

7: 63 mg / NaH / dimethylformamide / 20 °C

With sodium tetrahydroborate; sodium periodate; tetrabutylammomium bromide; water; sodium hydride; potassium carbonate; acetic acid; trifluoroacetic acid; bis(tri-n-butyltin)oxide; ruthenium trichloride; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1016/j.carres.2004.05.016

Reference yield:

: 642-38-6
quebrachitol

: 117708-51-7
((1R,2S,3S,4R,5S,6R)-2,3,4,5,6-Pentamethoxy-cyclohexyloxymethyl)-benzene

Guidance literature:: Multi-step reaction with 8 steps

1: H₂SO₄ / benzene; dimethylformamide

2: 100 percent / AcOH; H₂O / 4 h / 20 °C

3: 1.39 g / NaH / dimethylformamide / 20 °C

4: 0.96 g / TFA; H₂O / 20 °C

5: 320 mg / Bu₄NBr; (Bu₃Sn)2O / toluene / Heating

6: 162 mg / NaIO₄; K₂CO₃ / RuCl₃ / acetonitrile; CH₂Cl₂; H₂O / 20 °C

7: 122 mg / NaBH₄ / tetrahydrofuran; H₂O / 3 h / 20 °C

8: 63 mg / NaH / dimethylformamide / 20 °C

With sodium tetrahydroborate; sodium periodate; sulfuric acid; tetrabutylammomium bromide; water; sodium hydride; potassium carbonate; acetic acid; trifluoroacetic acid; bis(tri-n-butyltin)oxide; ruthenium trichloride; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; benzene;
DOI:10.1016/j.carres.2004.05.016

Reference yield:

: 17230-42-1
3,4,5,6-Tetra-O-methyl-(-)-inosit; L-(1,2,4-3,5,6)-3,4,5,6-Tetramethoxy-1,2-cyclohexandiol

: 117708-51-7
((1R,2S,3S,4R,5S,6R)-2,3,4,5,6-Pentamethoxy-cyclohexyloxymethyl)-benzene

Guidance literature:: Multi-step reaction with 4 steps

1: 320 mg / Bu₄NBr; (Bu₃Sn)2O / toluene / Heating

2: 162 mg / NaIO₄; K₂CO₃ / RuCl₃ / acetonitrile; CH₂Cl₂; H₂O / 20 °C

3: 122 mg / NaBH₄ / tetrahydrofuran; H₂O / 3 h / 20 °C

4: 63 mg / NaH / dimethylformamide / 20 °C

With sodium tetrahydroborate; sodium periodate; tetrabutylammomium bromide; sodium hydride; potassium carbonate; bis(tri-n-butyltin)oxide; ruthenium trichloride; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1016/j.carres.2004.05.016