C₆H₂(OH)(C(CH₃)3)2(P(C₆H₅)2NSi(CH₃)3)

Base Information

• Chemical Name: C₆H₂(OH)(C(CH₃)3)2(P(C₆H₅)2NSi(CH₃)3)
• CAS No.: 866563-77-1
• Molecular Formula: C₂₉H₄₀NOPSi
• Molecular Weight: 477.702
• Mol file: 866563-77-1.mol

Synonyms:C₆H₂(OH)(C(CH₃)3)2(P(C₆H₅)2NSi(CH₃)3)

Chemical Property of C₆H₂(OH)(C(CH₃)3)2(P(C₆H₅)2NSi(CH₃)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆H₂(OH)(C(CH₃)3)2(P(C₆H₅)2NSi(CH₃)3)

There total 1 articles about C₆H₂(OH)(C(CH₃)3)2(P(C₆H₅)2NSi(CH₃)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

trimethylsilylazide (4648-54-8) + (2-diphenylphosphanyl-4,6-di(tert-butyl))phenol (185509-32-4) → C6H2(OH)(C(CH3)3)2(P(C6H5)2NSi(CH3)3) (866563-77-1)

Guidance literature:

at 110 ℃; for 5h;

DOI:10.1016/j.jorganchem.2005.05.028

Reference yield: 93.0%

C6H2(OH)(C(CH3)3)2(P(C6H5)2NSi(CH3)3) (866563-77-1) + titanium tetrachloride (7550-45-0) → TiCl2(C6H2(O)(C(CH3)3)2(P(C6H5)2NSi(CH3)3))2 (866563-79-3)

Guidance literature:

With n-C₄H₉Li; In tetrahydrofuran; diethyl ether; under Ar atm. using Schlenk techniques; soln. of n-BuLi added dropwise to soln. of ligand in THF at -78°C; mixt. warmed to room temp.; stirred for 3 h; resulting soln. added to soln. of TiCl4 in Et2O at 78°C; mixt. stirred for 15 h at room; solvent removed (vac.); CH2Cl2 added; stirred for 30 min; filtered; filtrate concd. (vac.); hexane added; cooled slowly to -20°C; elem. anal.;

DOI:10.1016/j.jorganchem.2005.05.028

Reference yield: 88.0%

C6H2(OH)(C(CH3)3)2(P(C6H5)2NSi(CH3)3) (866563-77-1) + zirconium(IV) chloride (10026-11-6) → ZrCl2(C6H2(O)(C(CH3)3)2(P(C6H5)2NSi(CH3)3))2 (866563-80-6)

Guidance literature:

With n-C₄H₉Li; In tetrahydrofuran; diethyl ether; under Ar atm. using Schlenk techniques; soln. of n-BuLi added dropwise to soln. of ligand in THF at -78°C; mixt. warmed to room temp.; stirred for 3 h; resulting soln. added to soln. of TiCl4 in Et2O at 78°C; mixt. stirred for 15 h at room; solvent removed (vac.); CH2Cl2 added; stirred for 30 min; filtered; filtrate concd. (vac.); hexane added; cooled slowly to -20°C; elem. anal.;

DOI:10.1016/j.jorganchem.2005.05.028

upstream raw materials:

trimethylsilylazide

(2-diphenylphosphanyl-4,6-di(tert-butyl))phenol

Downstream raw materials:

TiCl₂(C₆H₂(O)(C(CH₃)3)2(P(C₆H₅)2NSi(CH₃)3))2

ZrCl₂(C₆H₂(O)(C(CH₃)3)2(P(C₆H₅)2NSi(CH₃)3))2