trans 1-(1-methyl 2-p-tolylvinyl)-1-trimethylsiloxycyclopropane

Base Information

Chemical Name:trans 1-(1-methyl 2-p-tolylvinyl)-1-trimethylsiloxycyclopropane
CAS No.:54158-58-6
Molecular Formula:C₁₆H₂₄OSi
Molecular Weight:260.451
Hs Code.:

Synonyms:trans 1-(1-methyl 2-p-tolylvinyl)-1-trimethylsiloxycyclopropane

Suppliers and Price of trans 1-(1-methyl 2-p-tolylvinyl)-1-trimethylsiloxycyclopropane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans 1-(1-methyl 2-p-tolylvinyl)-1-trimethylsiloxycyclopropane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans 1-(1-methyl 2-p-tolylvinyl)-1-trimethylsiloxycyclopropane

There total 4 articles about trans 1-(1-methyl 2-p-tolylvinyl)-1-trimethylsiloxycyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 75-77-4
chloro-trimethyl-silane

: 87325-98-2
trans-1-(1-methyl-2-p-tolylvinyl)cyclopropanol

: 54158-58-6
trans 1-(1-methyl 2-p-tolylvinyl)-1-trimethylsiloxycyclopropane

Guidance literature:: With dimethyl sulfoxide; triethylamine; In diethyl ether; for 4h;
DOI:10.1016/S0040-4020(01)91969-6

Reference yield:

: 87325-95-9
methyl(1-tetrahydropyranyloxycyclopropyl)ketone

: 54158-58-6
trans 1-(1-methyl 2-p-tolylvinyl)-1-trimethylsiloxycyclopropane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-butyllithium / 1.) tetrahydrofuran, hexane, room temp., 2 h, 2.) reflux, 16 h

2: 96 percent / PPTS / ethanol / 4 h / 55 °C

3: 86 percent / dimethylsulfoxide, triethylamine / diethyl ether / 4 h

With n-butyllithium; pyridinium p-toluenesulfonate; dimethyl sulfoxide; triethylamine; In diethyl ether; ethanol;
DOI:10.1016/S0040-4020(01)91969-6

Reference yield:

: 87325-96-0
trans-1-(1-methyl-2-p-tolylvinyl)-1-tetrahydropyranyloxycyclopropane

: 54158-58-6
trans 1-(1-methyl 2-p-tolylvinyl)-1-trimethylsiloxycyclopropane

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / PPTS / ethanol / 4 h / 55 °C

2: 86 percent / dimethylsulfoxide, triethylamine / diethyl ether / 4 h

With pyridinium p-toluenesulfonate; dimethyl sulfoxide; triethylamine; In diethyl ether; ethanol;
DOI:10.1016/S0040-4020(01)91969-6