D-1,5-di-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol

Base Information

Chemical Name:D-1,5-di-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol
CAS No.:200272-85-1
Molecular Formula:C₃₃H₃₄O₇
Molecular Weight:542.629
Hs Code.:

Synonyms:D-1,5-di-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol

Suppliers and Price of D-1,5-di-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of D-1,5-di-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of D-1,5-di-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol

There total 12 articles about D-1,5-di-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 65-85-0,8013-63-6
benzoic acid

: 161104-10-5
L-1-O-benzyl-5,6-O-cyclohexylidene-3-deoxy-chiro-inositol

: 200272-85-1
D-1,5-di-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; for 4h;
DOI:10.1016/S0040-4020(97)10101-6

Reference yield:

: 933-40-4
cycloxexanone dimethyl ketal

: 200272-85-1
D-1,5-di-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol

Guidance literature:: Multi-step reaction with 7 steps

1: 90 percent / H₂SO₄ / dimethylformamide / 12 h / Ambient temperature

2: 90 percent / triphenylphosphine, carbon tetrachloride, pyridine / 8 h / 60 °C

3: 1.) potassium hydroxide, benzyltrimethylammonium chloride / 1.) CH₂Cl₂, 10 min, 2.) CH₂Cl₂, 12 h

4: 60 percent / sodium hydride / dimethylformamide / 3 h / 110 °C

5: 1.) HgCl₂, 2.) thiourea / 1.) acetone-d6, D₂O, 20 min, 2.) acetone-d6, D₂O

6: 29 percent / cerium(III) chloride heptahydrate, sodium borohydride / methanol / Ambient temperature

7: 70 percent / triphenylphosphine, diisopropyl azodicarboxylate / tetrahydrofuran / 4 h

With pyridine; tetrachloromethane; potassium hydroxide; sodium tetrahydroborate; cerium(III) chloride; di-isopropyl azodicarboxylate; sulfuric acid; benzyltrimethylammonium chloride; sodium hydride; thiourea; triphenylphosphine; mercury dichloride; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(97)10101-6

Reference yield:

: 100-39-0
benzyl bromide

: 200272-85-1
D-1,5-di-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) potassium hydroxide, benzyltrimethylammonium chloride / 1.) CH₂Cl₂, 10 min, 2.) CH₂Cl₂, 12 h

2: 60 percent / sodium hydride / dimethylformamide / 3 h / 110 °C

3: 1.) HgCl₂, 2.) thiourea / 1.) acetone-d6, D₂O, 20 min, 2.) acetone-d6, D₂O

4: 29 percent / cerium(III) chloride heptahydrate, sodium borohydride / methanol / Ambient temperature

5: 70 percent / triphenylphosphine, diisopropyl azodicarboxylate / tetrahydrofuran / 4 h

With potassium hydroxide; sodium tetrahydroborate; cerium(III) chloride; di-isopropyl azodicarboxylate; benzyltrimethylammonium chloride; sodium hydride; thiourea; triphenylphosphine; mercury dichloride; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(97)10101-6