(N(SiMe₂CH₂PCy₂)2)ReH₄

Base Information

Chemical Name:(N(SiMe₂CH₂PCy₂)2)ReH₄
CAS No.:557085-22-0
Molecular Formula:C₃₀H₆₄NP₂ReSi₂
Molecular Weight:743.17
Hs Code.:

(N(SiMe<sub>2</sub>CH<sub>2</sub>PCy<sub>2</sub>)2)ReH<sub>4</sub>

Synonyms:(N(SiMe₂CH₂PCy₂)2)ReH₄

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Chemical Property of (N(SiMe₂CH₂PCy₂)2)ReH₄

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Technology Process of (N(SiMe₂CH₂PCy₂)2)ReH₄

There total 4 articles about (N(SiMe₂CH₂PCy₂)2)ReH₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: (N(SiMe₂CH₂PCy₂)2)ReOCl₂

: 1333-74-0
hydrogen

: 557085-22-0
(N(SiMe₂CH₂PCy₂)2)ReH₄

Guidance literature:: With Mg; In diethyl ether; suspn. (PNP(Cy))REOCl2 and Mg powder in ether was stirred under H2 atm. for 72 h; volatiles were removed in vacuo, residue was triturated with heptane, extd. with pentane and dried, filtrate was concd. in vacuo and kept at -30°C for 24 h, ppt. was washed with cold pentane and dried in vacuo;
DOI:10.1021/om0210412

Reference yield:

: (((C₆H₁₁)2PCH₂Si(CH₃)2)2N)ReO(H)2

: 1333-74-0
hydrogen

: 557085-22-0
(N(SiMe₂CH₂PCy₂)2)ReH₄

Guidance literature:: With Mg; In diethyl ether; under N2; Re complex in ether mixed with activated Mg powder under H2 (1atm);
DOI:10.1021/ja031617u

Reference yield:

: 597559-31-4,938170-64-0
(PNP(Cy))Re(H)2[cyclohexylidene]

: 938170-92-4
[Cy₂PCH₂SiMe₂NSiMe₂CH₂PCy(C₆H₈)]ReH

: 557085-22-0
(N(SiMe₂CH₂PCy₂)2)ReH₄

Guidance literature:: In neat (no solvent, solid phase); byproducts: C6H12, C6H10; at 120°C for 30 min in vac.; not isolated, detected by NMR;
DOI:10.1021/ja062327r