methyl 3-azido-4,6-O-benzylidene-3-deoxy-2-O-trifluoromethanesulphonyl-α-D-idopyranoside

Base Information

Chemical Name:methyl 3-azido-4,6-O-benzylidene-3-deoxy-2-O-trifluoromethanesulphonyl-α-D-idopyranoside
CAS No.:105600-36-0
Molecular Formula:C₁₅H₁₆F₃N₃O₇S
Molecular Weight:439.369
Hs Code.:

Synonyms:methyl 3-azido-4,6-O-benzylidene-3-deoxy-2-O-trifluoromethanesulphonyl-α-D-idopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 3-azido-4,6-O-benzylidene-3-deoxy-2-O-trifluoromethanesulphonyl-α-D-idopyranoside

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Technology Process of methyl 3-azido-4,6-O-benzylidene-3-deoxy-2-O-trifluoromethanesulphonyl-α-D-idopyranoside

There total 1 articles about methyl 3-azido-4,6-O-benzylidene-3-deoxy-2-O-trifluoromethanesulphonyl-α-D-idopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 3673-00-5
methyl 3-azido-4,6-O-benzylidene-3-deoxy-α-D-idopyranoside

: 358-23-6
trifluoromethylsulfonic anhydride

: 105600-36-0
methyl 3-azido-4,6-O-benzylidene-3-deoxy-2-O-trifluoromethanesulphonyl-α-D-idopyranoside

Guidance literature:: With pyridine; at 0 ℃; for 2h;
DOI:10.1016/S0008-6215(00)90313-6

Reference yield: 78.0%

: 105600-36-0
methyl 3-azido-4,6-O-benzylidene-3-deoxy-2-O-trifluoromethanesulphonyl-α-D-idopyranoside

: 105600-37-1
methyl 3-azido-4,6-O-benzylidene-2,3-dideoxy-2-fluoro-α-D-gulopyranoside

Guidance literature:: With tetrabutyl ammonium fluoride; In N,N-dimethyl-formamide; for 5h; Ambient temperature;
DOI:10.1016/S0008-6215(00)90313-6

Reference yield:

: 105600-36-0
methyl 3-azido-4,6-O-benzylidene-3-deoxy-2-O-trifluoromethanesulphonyl-α-D-idopyranoside

: 105600-40-6
methyl 3-acetamido-4-O-benzoyl-2,3,6-trideoxy-2-fluoro-β-L-mannopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 78 percent / tetrabutylammonium fluoride / dimethylformamide / 5 h / Ambient temperature

2: 56 percent / N-bromosuccinimide, BaCO₃ / CCl₄ / 1 h / Heating

3: 72 percent / silver fluoride / pyridine / 12 h / Ambient temperature

4: 60 percent / H₂ / 10percent Pd/C / methanol / 12 h

With N-Bromosuccinimide; tetrabutyl ammonium fluoride; hydrogen; silver fluoride; barium carbonate; palladium on activated charcoal; In pyridine; methanol; tetrachloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(00)90313-6