1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene

Base Information

Chemical Name:1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene
CAS No.:361525-05-5
Molecular Formula:C₂₅H₄₀Br₂O₂
Molecular Weight:532.399
Hs Code.:

Synonyms:1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene

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Chemical Property of 1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene

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Technology Process of 1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene

There total 1 articles about 1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 558-13-4
carbon tetrabromide

: 331625-96-8
(2R,3R,4S)-3-(4-Methoxy-benzyloxy)-2,4-dimethyl-tetradecanal

: 361525-05-5
1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene

Guidance literature:: With triphenylphosphine; In dichloromethane; at 20 ℃;
DOI:10.1021/jo0158128

Reference yield: 93.0%

: 361525-05-5
1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene

: 74-88-4
methyl iodide

: 361525-06-6
1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene

Guidance literature:: 1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene; With n-butyllithium; In tetrahydrofuran;

methyl iodide; at -78 ℃; Further stages.;
DOI:10.1021/jo0158128

Reference yield:

: 361525-05-5
1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene

: 2,2-Dimethyl-propionic acid (2E,6E,8E)-(4R,5R,10S,11R,12S)-11-hydroxy-2,4,6,8,10,12-hexamethyl-5-triphenylsilanyloxy-docosa-2,6,8-trienyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: BuLi / tetrahydrofuran

1.2: 93 percent / -78 °C

2.1: catecholborane / 50 °C

2.2: H₂O

3.1: 21 percent / TlOEt / Pd(PPh₃)4 / tetrahydrofuran; H₂O / 50 °C

With n-butyllithium; thallium (I) ethoxide; benzo[1,3,2]dioxaborole; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; water; 3.1: Suzuki coupling;
DOI:10.1021/jo0158128