(2S,3S)-3-benzyloxy-6-(tert-butyldiphenylsiloxy)-1,2-isopropylidenedioxyhexane

Base Information

Chemical Name:(2S,3S)-3-benzyloxy-6-(tert-butyldiphenylsiloxy)-1,2-isopropylidenedioxyhexane
CAS No.:115793-26-5
Molecular Formula:C₃₂H₄₂O₄Si
Molecular Weight:518.769
Hs Code.:

Synonyms:(2S,3S)-3-benzyloxy-6-(tert-butyldiphenylsiloxy)-1,2-isopropylidenedioxyhexane

Suppliers and Price of (2S,3S)-3-benzyloxy-6-(tert-butyldiphenylsiloxy)-1,2-isopropylidenedioxyhexane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3S)-3-benzyloxy-6-(tert-butyldiphenylsiloxy)-1,2-isopropylidenedioxyhexane

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Technology Process of (2S,3S)-3-benzyloxy-6-(tert-butyldiphenylsiloxy)-1,2-isopropylidenedioxyhexane

There total 6 articles about (2S,3S)-3-benzyloxy-6-(tert-butyldiphenylsiloxy)-1,2-isopropylidenedioxyhexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 115887-37-1
(4S,5S)-4-benzyloxy-5,6-isopropylidenedioxyhexan-1-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 115793-26-5
(2S,3S)-3-benzyloxy-6-(tert-butyldiphenylsiloxy)-1,2-isopropylidenedioxyhexane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 3h; Ambient temperature;
DOI:10.1248/cpb.37.2391

Reference yield:

: 84379-53-3
2-O-benzyl-3,4-O-isopropylidene-L-threitol

: 115793-26-5
(2S,3S)-3-benzyloxy-6-(tert-butyldiphenylsiloxy)-1,2-isopropylidenedioxyhexane

Guidance literature:: Multi-step reaction with 6 steps

1: Et₃N

2: NaI, NaHCO₃ / acetone

3: NaH / dimethylformamide

4: 87 percent / NaCl / dimethylsulfoxide; H₂O / 190 °C

5: 90 percent / LiAlH₄ / tetrahydrofuran / 2 h / Ambient temperature

6: 93 percent / imidazole / dimethylformamide / 3 h / Ambient temperature

With 1H-imidazole; lithium aluminium tetrahydride; sodium hydride; sodium hydrogencarbonate; triethylamine; sodium iodide; sodium chloride; In tetrahydrofuran; water; dimethyl sulfoxide; N,N-dimethyl-formamide; acetone;
DOI:10.1248/cpb.37.2391

Reference yield:

: 115689-98-0
<4S,4(1S)>-4-(1-Benzyloxy-2-iodoethyl)-2,2-dimethyl-1,3-dioxolane

: 115793-26-5
(2S,3S)-3-benzyloxy-6-(tert-butyldiphenylsiloxy)-1,2-isopropylidenedioxyhexane

Guidance literature:: Multi-step reaction with 4 steps

1: NaH / dimethylformamide

2: 87 percent / NaCl / dimethylsulfoxide; H₂O / 190 °C

3: 90 percent / LiAlH₄ / tetrahydrofuran / 2 h / Ambient temperature

4: 93 percent / imidazole / dimethylformamide / 3 h / Ambient temperature

With 1H-imidazole; lithium aluminium tetrahydride; sodium hydride; sodium chloride; In tetrahydrofuran; water; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1248/cpb.37.2391