(η2-C2H4)Pt(1,3-dicyclohexylphosphinopropane)

Base Information

• Chemical Name: (η2-C2H4)Pt(1,3-dicyclohexylphosphinopropane)
• CAS No.: 102286-40-8
• Molecular Formula: C₂₉H₅₄P₂Pt
• Molecular Weight: 659.775
• Mol file: 102286-40-8.mol

Synonyms:(η2-C2H4)Pt(1,3-dicyclohexylphosphinopropane)

Chemical Property of (η2-C2H4)Pt(1,3-dicyclohexylphosphinopropane)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η2-C2H4)Pt(1,3-dicyclohexylphosphinopropane)

There total 3 articles about (η2-C2H4)Pt(1,3-dicyclohexylphosphinopropane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.8%

bis[dicyclohexylphosphino]propane platinum (II) chloride (121122-18-7) + ethene (74-85-1) → (η2-C2H4)Pt(1,3-dicyclohexylphosphinopropane) (102286-40-8)

Guidance literature:

With sodium naphtalide; In tetrahydrofuran; hexane; High Pressure; sodium naphtalide soln. was added dropwise to soln. of (1,3-DCCP)PtCl2 at 0°C with stirring under N2, warmed up to room temp. under stirring for 3 h, solvent removed under vacuum, dissolved in warm hexane, subjected to 1000ψ of ethylene, 4 h; filtered, elem. anal.;;

DOI:10.1016/S0277-5387(00)80384-8

Reference yield:

1,3-bis(dicyclohexylphosphino)propaneplatinum(0) (102286-37-3) + ethene (74-85-1) → {1,3-bis(dicyclohexylphosphino)propane}(η2-ethylene)platinum(O) (102286-40-8)

Guidance literature:

In hexane; the soln. of Pt-complex in hexane reacted with ethylene gas under a pressure of 7 MPa;

Reference yield:

bis(cycloocta-1,5-diene)platinum(0) (12130-66-4) + ethene (74-85-1) + 1,3-bis(dicyclohexylphosphine)propane (103099-52-1) → (η2-C2H4)Pt(1,3-dicyclohexylphosphinopropane) (102286-40-8)

Guidance literature:

In hexane; addn. of Pt(cod)2 to soln. of diphosphine in ethene-satd. hexane at 273 K during 10 min. (N2); evapn. after 30 min. (vac.);

DOI:10.1039/DT9920002653

upstream raw materials:

1,3-bis(dicyclohexylphosphino)propaneplatinum⁽⁰⁾

ethene

bis(cycloocta-1,5-diene)platinum⁽⁰⁾

1,3-bis(dicyclohexylphosphine)propane

Downstream raw materials:

(C₆H₁₁)2P(CH₂)3P(C₆H₁₁)2Pt(H)C₂H₄⁽¹⁺⁾*BF₄^(1-)=(C₆H₁₁)2P(CH₂)3P(C₆H₁₁)2Pt(H)C₂H₄BF₄

(C₆H₁₁)2P(CH₂)3P(C₆H₁₁)2*Pt⁽²⁺⁾*2H^(1-)=(C₆H₁₁)2P(CH₂)3P(C₆H₁₁)2PtH₂