bis[dicyclohexylphosphino]propane platinum (II) chloride

Base Information

• Chemical Name: bis[dicyclohexylphosphino]propane platinum (II) chloride
• CAS No.: 121122-18-7
• Molecular Formula: C₂₇H₅₀Cl₂P₂Pt
• Molecular Weight: 702.628
• Mol file: 121122-18-7.mol

Synonyms:bis[dicyclohexylphosphino]propane platinum (II) chloride

Chemical Property of bis[dicyclohexylphosphino]propane platinum (II) chloride

Chemical Property:

Purity/Quality:

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Technology Process of bis[dicyclohexylphosphino]propane platinum (II) chloride

There total 3 articles about bis[dicyclohexylphosphino]propane platinum (II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,3-bis(dicyclohexylphosphine)propane (103099-52-1) → bis[dicyclohexylphosphino]propane platinum (II) chloride (121122-18-7)

Guidance literature:

In toluene; benzene; at 20 ℃; for 0.5h; Schlenk technique; Inert atmosphere; Glovebox;

DOI:10.1002/chem.201301056

Reference yield:

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,3-bis(dicyclohexylphosphine)propane (103099-52-1) → bis[dicyclohexylphosphino]propane platinum (II) chloride (121122-18-7)

Guidance literature:

In not given; displacement fo cyclooctadiene;

DOI:10.1016/S0277-5387(00)86908-9

Reference yield:

((P(C6H11)2)2(CH2)3)Pt(CH2Cl)2 → bis[dicyclohexylphosphino]propane platinum (II) chloride (121122-18-7)

Guidance literature:

In chloroform-d1; about 2 weeks; detected by NMR;

DOI:10.1039/DT9910000949

upstream raw materials:

dichloro(1,5-cyclooctadiene)platinum(ll)

1,3-bis(dicyclohexylphosphine)propane

dichloro( 1,5-cyclooctadiene)platinum(ll)

Downstream raw materials:

(η2-C2H4)Pt(1,3-dicyclohexylphosphinopropane)

Pt(CH₂CHC₆H₅)((C₆H₁₁)2P(CH₂)3P(C₆H₁₁)2)

bis[dicyclohexylphosphino]propane platinum (II) hydrido meta toluene