2-(1-Benzyloxymethylpenta-2,4-dienyl)-3-fluoro-6-methoxy-5-methyl-1,4-benzoquinone

Base Information

Chemical Name:2-(1-Benzyloxymethylpenta-2,4-dienyl)-3-fluoro-6-methoxy-5-methyl-1,4-benzoquinone
CAS No.:116589-05-0
Molecular Formula:C₂₁H₂₁FO₄
Molecular Weight:356.394
Hs Code.:

Synonyms:2-(1-Benzyloxymethylpenta-2,4-dienyl)-3-fluoro-6-methoxy-5-methyl-1,4-benzoquinone

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Chemical Property of 2-(1-Benzyloxymethylpenta-2,4-dienyl)-3-fluoro-6-methoxy-5-methyl-1,4-benzoquinone

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Technology Process of 2-(1-Benzyloxymethylpenta-2,4-dienyl)-3-fluoro-6-methoxy-5-methyl-1,4-benzoquinone

There total 12 articles about 2-(1-Benzyloxymethylpenta-2,4-dienyl)-3-fluoro-6-methoxy-5-methyl-1,4-benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 116589-04-9
2(1-Benzyloxymethylpenta-2,4-dienyl)-3-fluoro-4,6-dimethoxy-5-methylphenol

: 116589-05-0
2-(1-Benzyloxymethylpenta-2,4-dienyl)-3-fluoro-6-methoxy-5-methyl-1,4-benzoquinone

Guidance literature:: With ammonium cerium(IV) nitrate; In water; acetonitrile; at 0 ℃; for 0.05h;

Reference yield:

: 3587-60-8
Benzyloxymethyl chloride

: 116589-05-0
2-(1-Benzyloxymethylpenta-2,4-dienyl)-3-fluoro-6-methoxy-5-methyl-1,4-benzoquinone

Guidance literature:: Multi-step reaction with 2 steps

1: 55 percent / n-BuLi / tetrahydrofuran / -75 - 0 °C

2: 69 percent / cerium(IV) ammonium nitrate / H₂O; acetonitrile / 0.05 h / 0 °C

With n-butyllithium; ammonium cerium(IV) nitrate; In tetrahydrofuran; water; acetonitrile;

Reference yield:

: 7149-92-0
2,4-dimethoxy-3-methylbenzaldehyde

: 116589-05-0
2-(1-Benzyloxymethylpenta-2,4-dienyl)-3-fluoro-6-methoxy-5-methyl-1,4-benzoquinone

Guidance literature:: Multi-step reaction with 10 steps

1: 80 percent / Br₂

2: 1.) m-chloroperbenzoic acid, 2.) KOH / 2.) MeOH

3: NaH / dimethylformamide

4: n-BuLi, perchloryl fluoride / diethyl ether

5: HCl / acetone

6: 83 percent / K₂CO₃ / acetone

7: 62 percent / AlCl₃*OEt₂ / CH₂Cl₂ / 1 h / -25 °C

8: NaH

9: 55 percent / n-BuLi / tetrahydrofuran / -75 - 0 °C

10: 69 percent / cerium(IV) ammonium nitrate / H₂O; acetonitrile / 0.05 h / 0 °C

With hydrogenchloride; potassium hydroxide; n-butyllithium; ammonium cerium(IV) nitrate; perchloryl fluoride; AlCl₃ etherate; bromine; sodium hydride; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone; acetonitrile;