methyl 14-(2,5-dichlorophenyloxy)-3,6,9,12-tetraoxatetradecanoate

Base Information

• Chemical Name: methyl 14-(2,5-dichlorophenyloxy)-3,6,9,12-tetraoxatetradecanoate
• CAS No.: 872410-00-9
• Molecular Formula: C₁₇H₂₄Cl₂O₇
• Molecular Weight: 411.279
• Mol file: 872410-00-9.mol

Synonyms:methyl 14-(2,5-dichlorophenyloxy)-3,6,9,12-tetraoxatetradecanoate

Chemical Property of methyl 14-(2,5-dichlorophenyloxy)-3,6,9,12-tetraoxatetradecanoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 14-(2,5-dichlorophenyloxy)-3,6,9,12-tetraoxatetradecanoate

There total 4 articles about methyl 14-(2,5-dichlorophenyloxy)-3,6,9,12-tetraoxatetradecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-{2-[2-(2-{2-methoxycarbomethoxy}-ethoxy)-ethoxy]-ethoxy}yl p-toluenesulfonate (872409-96-6) + 2,5-dichlorophenol (583-78-8) → methyl 14-(2,5-dichlorophenyloxy)-3,6,9,12-tetraoxatetradecanoate (872410-00-9)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; potassium carbonate; In acetonitrile; Heating;

DOI:10.1021/ja0535357

Reference yield:

methyl 14-hydroxy-3,6,9,12-tetraoxatetradecanoate (77303-64-1) → methyl 14-(2,5-dichlorophenyloxy)-3,6,9,12-tetraoxatetradecanoate (872410-00-9)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine

2: K₂CO₃

With pyridine; potassium carbonate;

DOI:10.1002/anie.200460762

Reference yield:

Tetraethylene glycol (112-60-7) → methyl 14-(2,5-dichlorophenyloxy)-3,6,9,12-tetraoxatetradecanoate (872410-00-9)

Guidance literature:

Multi-step reaction with 4 steps

1.1: Na

1.2: 10 h / 100 °C

2.1: H₂SO₄ / 10 h / Heating

3.1: pyridine / cooling

4.1: 15.0 g / K₂CO₃; (n-Bu)4NI / acetonitrile / Heating

With pyridine; sulfuric acid; sodium; tetra-(n-butyl)ammonium iodide; potassium carbonate; In acetonitrile;

DOI:10.1021/ja0535357

upstream raw materials:

2-{2-[2-(2-{2-methoxycarbomethoxy}-ethoxy)-ethoxy]-ethoxy}yl p-toluenesulfonate

2,5-dichlorophenol

methyl 14-hydroxy-3,6,9,12-tetraoxatetradecanoate

Tetraethylene glycol