molybdenum(VI) dibromide dioxide

Base Information

• Chemical Name: molybdenum(VI) dibromide dioxide
• CAS No.: 13595-98-7
• Molecular Formula: Br₂MoO₂
• Molecular Weight: 287.747
• Mol file: 13595-98-7.mol

Synonyms:molybdenum(VI) dibromide dioxide

Chemical Property of molybdenum(VI) dibromide dioxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of molybdenum(VI) dibromide dioxide

There total 1 articles about molybdenum(VI) dibromide dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

molybdenum(IV) oxide + carbonyl dibromide (593-95-3) → molybdenum(VI) dibromide dioxide (13595-98-7)

Guidance literature:

In neat (no solvent); byproducts: CO; condensing COBr2 onto MoO2, heating (sealed tube, 125°C, 10 d); cooling the tube to -95°C, removal of volatiles (vac.); elem. anal.;

Reference yield: 92.0%

molybdenum(VI) dibromide dioxide (13595-98-7) + benzonitrile (100-47-0) → MoBr2O2(C6H5CN)2 (235105-24-5)

Guidance literature:

In neat (no solvent); Ar-atmosphere; in neat nitrile, room temp., 10 min; filtration, evapn.; elem. anal.;

Reference yield:

molybdenum(VI) dibromide dioxide (13595-98-7) + N,N'-bis(benzyliden)ethylendiamine (104-71-2) → (N,N'-bis(benzylidene)ethylenediamine)-dibromodioxomolybdenum(VI)

Guidance literature:

In acetonitrile; under N2; soln. of BED (0.57 mmol) in MeCN added dropwise to soln. of MoO2Br2 (0.57 mmol) in MeCN, mixt. heated to reflux, left to cool slowly overnight; decanted from crystals, recrystd. (MeCN);

DOI:10.1016/j.molcata.2004.10.004

upstream raw materials:

carbonyl dibromide

Downstream raw materials:

MoBr₂O₂(C₆H₅CN)2