N-{(1S,2E)-4-(benzyloxy)-1-[(1S,2E)-3-iodo-1-methylprop-2-en-1-yl]-2-methylbut-2-en-1-yl}-N-methyl-2-nitroaniline

Base Information

Chemical Name:N-{(1S,2E)-4-(benzyloxy)-1-[(1S,2E)-3-iodo-1-methylprop-2-en-1-yl]-2-methylbut-2-en-1-yl}-N-methyl-2-nitroaniline
CAS No.:1072091-36-1
Molecular Formula:C₂₃H₂₇IN₂O₅S
Molecular Weight:570.448
Hs Code.:

Synonyms:N-{(1S,2E)-4-(benzyloxy)-1-[(1S,2E)-3-iodo-1-methylprop-2-en-1-yl]-2-methylbut-2-en-1-yl}-N-methyl-2-nitroaniline

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Chemical Property of N-{(1S,2E)-4-(benzyloxy)-1-[(1S,2E)-3-iodo-1-methylprop-2-en-1-yl]-2-methylbut-2-en-1-yl}-N-methyl-2-nitroaniline

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Technology Process of N-{(1S,2E)-4-(benzyloxy)-1-[(1S,2E)-3-iodo-1-methylprop-2-en-1-yl]-2-methylbut-2-en-1-yl}-N-methyl-2-nitroaniline

There total 9 articles about N-{(1S,2E)-4-(benzyloxy)-1-[(1S,2E)-3-iodo-1-methylprop-2-en-1-yl]-2-methylbut-2-en-1-yl}-N-methyl-2-nitroaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1072091-35-0
N-{(1S,2E)-4-(benzyloxy)-1-[(1S,2E)-3-iodo-1-methylprop-2-en-1-yl]-2-methylbut-2-en-1-yl}-2-nitroaniline

: 74-88-4
methyl iodide

: 1072091-36-1
N-{(1S,2E)-4-(benzyloxy)-1-[(1S,2E)-3-iodo-1-methylprop-2-en-1-yl]-2-methylbut-2-en-1-yl}-N-methyl-2-nitroaniline

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 68h;

Reference yield:

: 1072091-12-3
(2R,3S,4E)-6-(benzyloxy)-3-[(4-methoxyphenyl)amino]-2,4-dimethylhex-4-en-1-ol

: 1072091-36-1
N-{(1S,2E)-4-(benzyloxy)-1-[(1S,2E)-3-iodo-1-methylprop-2-en-1-yl]-2-methylbut-2-en-1-yl}-N-methyl-2-nitroaniline

Guidance literature:: Multi-step reaction with 6 steps

1.1: sulfuric acid; periodic acid / water; acetonitrile / 1.5 h / 20 °C

1.2: 8 h / 20 °C

2.1: Dess-Martin periodane / dichloromethane / 0.17 h / 20 °C

3.1: chromium dichloride / tetrahydrofuran / 5.5 h / 0 - 20 °C

4.1: hydrogenchloride / ethyl acetate / 1 h / 20 °C

5.1: triethylamine / dichloromethane / 3 h / 20 °C

6.1: potassium carbonate / N,N-dimethyl-formamide / 68 h / 20 °C

With chromium dichloride; hydrogenchloride; sulfuric acid; potassium carbonate; Dess-Martin periodane; periodic acid; triethylamine; In tetrahydrofuran; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; acetonitrile;

Reference yield:

: 1072091-14-5
tert-butyl {(1S,2E)-4-(benzyloxy)-1-[(1R)-2-hydroxy-1-methylethyl]-2-methylbut-2-en-1-yl}carbamate

: 1072091-36-1
N-{(1S,2E)-4-(benzyloxy)-1-[(1S,2E)-3-iodo-1-methylprop-2-en-1-yl]-2-methylbut-2-en-1-yl}-N-methyl-2-nitroaniline

Guidance literature:: Multi-step reaction with 5 steps

1: Dess-Martin periodane / dichloromethane / 0.17 h / 20 °C

2: chromium dichloride / tetrahydrofuran / 5.5 h / 0 - 20 °C

3: hydrogenchloride / ethyl acetate / 1 h / 20 °C

4: triethylamine / dichloromethane / 3 h / 20 °C

5: potassium carbonate / N,N-dimethyl-formamide / 68 h / 20 °C

With chromium dichloride; hydrogenchloride; potassium carbonate; Dess-Martin periodane; triethylamine; In tetrahydrofuran; dichloromethane; ethyl acetate; N,N-dimethyl-formamide;