Os(SiMe2OH)(κ(2)-S2CNMe2)(CO)(PPh3)2

Base Information

Chemical Name:Os(SiMe2OH)(κ(2)-S2CNMe2)(CO)(PPh3)2
CAS No.:850219-98-6
Molecular Formula:C₄₂H₄₃NO₂OsP₂S₂Si
Molecular Weight:938.174
Hs Code.:

Synonyms:Os(SiMe2OH)(κ(2)-S2CNMe2)(CO)(PPh3)2

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Chemical Property of Os(SiMe2OH)(κ(2)-S2CNMe2)(CO)(PPh3)2

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Technology Process of Os(SiMe2OH)(κ(2)-S2CNMe2)(CO)(PPh3)2

There total 3 articles about Os(SiMe2OH)(κ(2)-S2CNMe2)(CO)(PPh3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 75-09-2
dichloromethane

: Os(SiMe2Cl)(κ(2)-S2CNMe2)(CO)(PPh3)2*1/3CH2Cl2

: 57138-17-7,850331-52-1
Os(κ(2)-S2CNMe2)Cl(CO)(PPh3)2

: 850219-98-6
Os(SiMe2OH)(κ(2)-S2CNMe2)(CO)(PPh3)2

Guidance literature:: With silica; In dichloromethane; acetone; soln. Os(SiMe2Cl)(κ2-S2CNMe2)(CO)(PPh3)2 in CH2Cl2 was placed on silica column and eluted with acetone; solvent was removed, residue was dissolved in CH2Cl2 and purified by column chromy. on silica (acetone-hexane 1:3), recrystn. from CH2Cl2-EtOH; elem. anal.;
DOI:10.1016/j.ica.2004.07.058

Reference yield: 36.0%

: Os(SiMe2Cl)(κ(2)-S2CNMe2)(CO)(PPh3)2*1/3CH2Cl2

: 7732-18-5
water

: potassium hydroxide

: 56800-92-1
OsH(κ(2)-S2CNMe2)(CO)(PPh3)2

: 850219-98-6
Os(SiMe2OH)(κ(2)-S2CNMe2)(CO)(PPh3)2

: 850220-04-1
Os[Si(OH)3](κ(2)-S2CNMe2)(CO)(PPh3)2*H2O

Guidance literature:: In tetrahydrofuran; water; Os(SiMe2Cl)(κ2-S2CNMe2)(CO)(PPh3)2 in THF was treated with KOH in water at 60°C for 16 h; volatiles were removed in vacuo, residue was taken up in CH2Cl2, dried over Na2SO4, filtered, concd., and chromed. on silica (acetone-hexane 1:3), recrystn. from CH2Cl2-heptane; elem. anal.;
DOI:10.1016/j.ica.2004.07.058

Reference yield: 1.0%

: Os(SiMe2Cl)(κ(2)-S2CNMe2)(CO)(PPh3)2*1/3CH2Cl2

: 1310-73-2
sodium hydroxide

: 850219-98-6
Os(SiMe2OH)(κ(2)-S2CNMe2)(CO)(PPh3)2

Guidance literature:: In tetrahydrofuran; water; to soln. Os(SiMe2Cl)(κ2-S2CNMe2)(CO)(PPh3)2 in THF aq. soln. NaOH was added and stirred at room temp.;
DOI:10.1016/j.ica.2004.07.058