N-benzyl-N-diphenylphosphanyl-p-trifluoromethylphenylsulfinamide borane complex

Base Information

Chemical Name:N-benzyl-N-diphenylphosphanyl-p-trifluoromethylphenylsulfinamide borane complex
CAS No.:1224969-62-3
Molecular Formula:C₂₆H₂₄BF₃NOPS
Molecular Weight:497.329
Hs Code.:

Synonyms:N-benzyl-N-diphenylphosphanyl-p-trifluoromethylphenylsulfinamide borane complex

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Chemical Property of N-benzyl-N-diphenylphosphanyl-p-trifluoromethylphenylsulfinamide borane complex

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Technology Process of N-benzyl-N-diphenylphosphanyl-p-trifluoromethylphenylsulfinamide borane complex

There total 2 articles about N-benzyl-N-diphenylphosphanyl-p-trifluoromethylphenylsulfinamide borane complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: N-benzyl-4-(trifluoromethyl)benzenesulfinamide

: 13292-87-0
dimethyl sulfide borane

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 1224969-62-3
N-benzyl-N-diphenylphosphanyl-p-trifluoromethylphenylsulfinamide borane complex

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; byproducts: H2; (N2), sulfinamide treated with dry THF, cooled to -78°C, treated with BuLi in hexanes, stirred for 15 min, treated dropwise with 1.2 equiv. of Ph2PC, stirred for 1 h, warmed to -30°C, treated with BH3*SMe2, stirred for 20 min; warmed to 0°C, treated with h2O and Et2O, aq. layer washed (Et2O), org. layer dried (MgSO4), filtered, concd.(vac.), chromy.(silica gel -hexane/EtOAc 90:10), elem. anal.;
DOI:10.1002/ejic.200900521

Reference yield:

: C₂₆H₂₁F₃NOPS

: 1224969-62-3
N-benzyl-N-diphenylphosphanyl-p-trifluoromethylphenylsulfinamide borane complex

Guidance literature:: With dimethylsulfide borane complex; In tetrahydrofuran; hexane; at -30 - 0 ℃; Inert atmosphere;
DOI:10.1002/ejic.200900521

Reference yield: 77.0%

: 57032-12-9
1-trimethylsilylacetylenehexacarbonyldicobalt

: 1224969-62-3
N-benzyl-N-diphenylphosphanyl-p-trifluoromethylphenylsulfinamide borane complex

: 1224969-66-7
dicobalttetracarbonyl(μ-trimethylsilylacetylene)(μ2-P,S-N-benzyl-p-trifluoromethylphenylsulfinamide)

Guidance literature:: With 1,4-diaza-bicyclo[2.2.2]octane; In toluene; (N2) borane protected sulfinamide, 1,4-diazabicyclo(2.2.2)octane and Co complex (1:1.1:1) treated with toluene, heated at 40°C for 3 h, at 65°C for 2 h; concd.(vac.), chromy.(silica gel - hexanes/EtOH 95:5), elem. anal.;
DOI:10.1002/ejic.200900521