Cr(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)₂

Base Information

Chemical Name:Cr(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)₂
CAS No.:390366-82-2
Molecular Formula:C₄₇H₁₈CrF₁₅N₆
Molecular Weight:1003.67
Hs Code.:

Cr(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)<SUB>2</SUB>

Synonyms:Cr(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)₂

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Chemical Property of Cr(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)₂

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Technology Process of Cr(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)₂

There total 2 articles about Cr(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.7%

: 110-86-1
pyridine

: oxo[5,10,15-tris(pentafluorophenyl)corrolato]chromium(V)

: 390366-82-2
Cr(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)₂

Guidance literature:: With PPh₃; In dichloromethane; Cr-complex was dissolved in CH2Cl2-pyridine in the presence of PPh3, stirred for several h; solvent was evapd., dissolved in hexane-CH2Cl2-pyridine, eluted through silica gel, collected, recrystd. from CH2Cl2/pyridine;
DOI:10.1021/ic010723z

Reference yield: 70.0%

: 110-86-1
pyridine

: chromium dichloride

: 238402-21-6
5,10,15-tris(pentafluorophenyl)corrole

: 390366-82-2
Cr(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)₂

Guidance literature:: In benzene; ligand was dissolved in pyridine, heated to reflux under Ar, CrCl2 was added, 2 h, dissolved in benzene-pyridine; filtered, silica gel was added, solvent was evapd., column chromy. on silica gel with hexane-CH2Cl2-pyridine, recrystd. from benzene-heptane with pyridine; elem. anal.;
DOI:10.1021/ic010723z

Reference yield: 62.0%

: 390366-82-2
Cr(5,10,15-tris(pentafluorophenyl)corrole)(pyridine)₂

: 14213-00-4
2,4,6-trimethylaniline azide

: 852529-64-7
Cr(tris(pentafluorophenyl)corrole^(3-))(N-2,4,6-(CH₃)3C₆H₂)

Guidance literature:: In toluene; mesityl azide added to a soln. of Cr complex under Ar, refluxed for ca. 3.5 h; evapd. (vac.), chromd. (silica gel, pentane/ether), recrystd. (aerobically, pentane/toluene);
DOI:10.1021/ic0484506